Assembly of a two-dimensional oxalate-bridged heterometallic Co II3CrIII2 coordination polymer

Hui Zhong Kou; Jun Tao; Osamu Sato

doi:10.1039/b800659h

Assembly of a two-dimensional oxalate-bridged heterometallic Co ^II₃Cr^III₂ coordination polymer

Hui Zhong Kou, Jun Tao, Osamu Sato

物質基盤化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

7 被引用数 (Scopus)

抄録

Reaction of CoCl₂•4H₂O with Ag ₃[Cr(ox)₃] (3:mol/mol) in methanol gives rise to an oxalate-bridged complex [Co(MeOH)₂]₃[Cr(ox) ₃]₂•6MeOH that consists of a rare cloverleaf-like layered structure (12,3-net). Ferromagnetic coupling is operative between the adjacent metal ions through the oxalate bridges.

本文言語	英語
ページ（範囲）	3652-3656
ページ数	5
ジャーナル	Dalton Transactions
号	28
DOI	https://doi.org/10.1039/b800659h
出版ステータス	出版済み - 2008

!!!All Science Journal Classification (ASJC) codes

無機化学

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10.1039/b800659h

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引用スタイル

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title = "Assembly of a two-dimensional oxalate-bridged heterometallic Co II3CrIII2 coordination polymer",

abstract = "Reaction of CoCl2•4H2O with Ag 3[Cr(ox)3] (3:mol/mol) in methanol gives rise to an oxalate-bridged complex [Co(MeOH)2]3[Cr(ox) 3]2•6MeOH that consists of a rare cloverleaf-like layered structure (12,3-net). Ferromagnetic coupling is operative between the adjacent metal ions through the oxalate bridges.",

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AB - Reaction of CoCl2•4H2O with Ag 3[Cr(ox)3] (3:mol/mol) in methanol gives rise to an oxalate-bridged complex [Co(MeOH)2]3[Cr(ox) 3]2•6MeOH that consists of a rare cloverleaf-like layered structure (12,3-net). Ferromagnetic coupling is operative between the adjacent metal ions through the oxalate bridges.

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