Asymmetric hydrosilylation of symmetrical diketones catalyzed by a rhodium complex with trans-chelating chiral diphosphine EtTRAP

Ryoichi Kuwano, Masaya Sawamura, Junya Shirai, Masatoshi Takahashi, Yoshihiko Ito

研究成果: ジャーナルへの寄稿記事

45 引用 (Scopus)

抜粋

Asymmetric hydrosilylation of symmetrical diketones with diphenylsilane in the presence of catalytic amount ([substrate]/[catalyst] = 100) of rhodium complex coordinated with trans-chelating chiral phosphine ligand EtTRAP gave corresponding optically active symmetrical diols with high enantiomeric excesses.

元の言語英語
ページ(範囲)5239-5242
ページ数4
ジャーナルTetrahedron Letters
36
発行部数29
DOI
出版物ステータス出版済み - 7 17 1995
外部発表Yes

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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