Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water

Yasuro Niidome; Takashi Kawazoe; Sunao Yamada

Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water

Yasuro Niidome, Takashi Kawazoe, Sunao Yamada

研究成果: ジャーナルへの寄稿 › 会議記事 › 査読

抄録

One surface of a very thin poly(maleic anhydride-alt-1-octadecene)(PMAO) film was treated with an SHG-active dye (Disperse Orange3:DO3) on water. The DO3-treated PMAO film showed a clear second harmonic generation (SHG) response. It is suggested that the asymmetric incorporation is achieved by taking the form of -CO₂^-N⁺H₃-between the amino group of DO3 and the carboxyl group of PMAO formed by hydrolysis of maleic anhydride moiety. The results were compared with those in poly(methyl methacrylate) and poly(vinyl chloride) films having less and no SHG responses, respectively.

本文言語	英語
ページ（範囲）	119-122
ページ数	4
ジャーナル	Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics
巻	22
号	1-4
出版ステータス	出版済み - 12月 1 1999
イベント	Proceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference - Chitose, Jpn 継続期間: 10月 12 1998 → 10月 15 1998

!!!All Science Journal Classification (ASJC) codes

制御およびシステム工学
凝縮系物理学

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title = "Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water",

abstract = "One surface of a very thin poly(maleic anhydride-alt-1-octadecene)(PMAO) film was treated with an SHG-active dye (Disperse Orange3:DO3) on water. The DO3-treated PMAO film showed a clear second harmonic generation (SHG) response. It is suggested that the asymmetric incorporation is achieved by taking the form of -CO2-N+H3-between the amino group of DO3 and the carboxyl group of PMAO formed by hydrolysis of maleic anhydride moiety. The results were compared with those in poly(methyl methacrylate) and poly(vinyl chloride) films having less and no SHG responses, respectively.",

author = "Yasuro Niidome and Takashi Kawazoe and Sunao Yamada",

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note = "Proceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference ; Conference date: 12-10-1998 Through 15-10-1998",

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TY - JOUR

T1 - Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water

AU - Niidome, Yasuro

AU - Kawazoe, Takashi

AU - Yamada, Sunao

PY - 1999/12/1

Y1 - 1999/12/1

N2 - One surface of a very thin poly(maleic anhydride-alt-1-octadecene)(PMAO) film was treated with an SHG-active dye (Disperse Orange3:DO3) on water. The DO3-treated PMAO film showed a clear second harmonic generation (SHG) response. It is suggested that the asymmetric incorporation is achieved by taking the form of -CO2-N+H3-between the amino group of DO3 and the carboxyl group of PMAO formed by hydrolysis of maleic anhydride moiety. The results were compared with those in poly(methyl methacrylate) and poly(vinyl chloride) films having less and no SHG responses, respectively.

AB - One surface of a very thin poly(maleic anhydride-alt-1-octadecene)(PMAO) film was treated with an SHG-active dye (Disperse Orange3:DO3) on water. The DO3-treated PMAO film showed a clear second harmonic generation (SHG) response. It is suggested that the asymmetric incorporation is achieved by taking the form of -CO2-N+H3-between the amino group of DO3 and the carboxyl group of PMAO formed by hydrolysis of maleic anhydride moiety. The results were compared with those in poly(methyl methacrylate) and poly(vinyl chloride) films having less and no SHG responses, respectively.

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VL - 22

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EP - 122

JO - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

JF - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

SN - 1543-0537

IS - 1-4

T2 - Proceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference

Y2 - 12 October 1998 through 15 October 1998

ER -

Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water

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!!!All Science Journal Classification (ASJC) codes

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