Atomic locations of minor dopants and their roles in the stabilization of η- C u6 S n5

Wenhui Yang, Xuan Quy Tran, Tomokazu Yamamoto, Satoru Yoshioka, Flora Somidin, Kazuhiro Nogita, Syo Matsumura

研究成果: Contribution to journalArticle査読


Chemical modification using only small amounts of elements such as Zn, In, Sb, or Ni has proven to be an effective means to control the desirable crystal structure of hexagonal η-Cu6Sn5 over a wide thermally operating window, typically found in Pb-free Sn-based soldering or Li-ion battery anode applications. Though appealing, the underlying mechanisms on the role of these dopants remain incomplete and their atomic arrangements within the η-Cu6Sn5 lattices have not yet been experimentally determined. In the current study, we directly reveal the atomic positions of Zn, In, and Sb at the Sn sites of η-Cu6Sn5 via atomic-scale x-ray energy dispersive spectroscopy (XEDS) maps utilizing advanced Cs-corrected scanning transmission electron microscopy. The use of advanced statistical algorithms including Poisson non-local principal component analysis and lattice averaging enables the fine resolution of weak XEDS maps from trace dopant elements. Our first-principles calculations further identify the influence of dopants at these atomic sites on the overall energetics, electronic structures, as well as local bonding environments, leading to the most favorable situations for η-Cu6Sn5 stabilization.

ジャーナルPhysical Review Materials
出版ステータス出版済み - 6 2020

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Physics and Astronomy (miscellaneous)

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