Au(I) complexes-catalyzed transfer vinylation of alcohols and carboxylic acids

Aki Nakamura, Makoto Tokunaga

研究成果: Contribution to journalArticle査読

28 被引用数 (Scopus)

抄録

Au(I) complexes-catalyzed transfer vinylation of alcohols and carboxylic acids has been achieved. The catalyst system consists of 2 mol % AuClPPh3 and 2 mol % AgOAc. Primary alcohols and secondary alcohols were converted into corresponding vinyl ethers in good yield (64-93%); however, tertiary alcohols showed poor reactivities. Carboxylic acids were also transformed into corresponding vinyl esters in good yield (78-96%).

本文言語英語
ページ(範囲)3729-3732
ページ数4
ジャーナルTetrahedron Letters
49
23
DOI
出版ステータス出版済み - 6 2 2008

All Science Journal Classification (ASJC) codes

  • 生化学
  • 創薬
  • 有機化学

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