Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

Shogo Kuriyama, Kazuya Arashiba, Kazunari Nakajima, Hiromasa Tanaka, Kazunari Yoshizawa, Yoshiaki Nishibayashi

研究成果: Contribution to journalArticle査読

30 被引用数 (Scopus)

抄録

A series of azaferrocene-based PNP-type pincer ligands were designed and prepared as new PNP-type pincer ligands. Some transition-metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene-based PNP-type pincer ligands were also prepared and characterized by X-ray analysis. The stoichiometric and catalytic reactivities of molybdenum–dinitrogen complexes toward nitrogen fixation were investigated in detail.

本文言語英語
ページ(範囲)4856-4861
ページ数6
ジャーナルEuropean Journal of Inorganic Chemistry
2016
30
DOI
出版ステータス出版済み - 10 2016

All Science Journal Classification (ASJC) codes

  • 無機化学

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