Binary organogelators which show light and temperature responsiveness

Masatsugu Ayabe, Takanori Kishida, Norifumi Fujita, Kazuki Sada, Seiji Shinkai

研究成果: Contribution to journalArticle査読

118 被引用数 (Scopus)

抄録

The gelation ability of 10 alkylammonium (CnH2n + 1 1NH3+ where n = 4-11, 12 and 16) anthracene-9-carboxylates (1n) has been evaluated. In cyclohexane, 14, 15, 16 and 17 only provided precipitates whereas 111, 112 and 116 provided very viscous solutions. In contrast, 18, 19 and 1 10 resulted in gels. The critical gelation concentration of 1 10 was very low (5.0 × 10-4 mol dm-3). SEM observations showed that in the gel phase the morphology changes from straight fibrils to frizzy fibrils with the increase in n, whereas in the sol phase the formation of the sheet-like, two-dimensional aggregate is recognized. When the cyclohexane 110 gel was photoirradiated (λ > 300 nm), the UV-VIS absorption bands assignable to monomeric anthracene were decreased and the gel was changed into the sol. It was confirmed by dark-field optical microscopy that the fibrillar bundles supporting the gel formation gradually disappear with photoirradiation time. When this sol was warmed at 30 °C in the dark, the gel was not regenerated but the precipitation of 1 10, resulted. When this sol was heated once at the bp of cyclohexane and cooled to 15 °C, the solution was changed into the gel again. This finding indicates that the fibrillar structure required for the gel formation is not reconstructed at 30 °C but obtained only when the hot cyclohexane solution is cooled.

本文言語英語
ページ(範囲)2744-2747
ページ数4
ジャーナルOrganic and Biomolecular Chemistry
1
15
DOI
出版ステータス出版済み - 8 7 2003

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

フィンガープリント 「Binary organogelators which show light and temperature responsiveness」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル