Bioinspired Approach to Silica Nanoparticle Synthesis Using Amine-Containing Block Copoly(vinyl ethers): Realizing Controlled Anisotropy

Ayae Sugawara-Narutaki, Sachio Tsuboike, Yukari Oda, Atsushi Shimojima, Kira B. Landenberger, Tatsuya Okubo, Sadahito Aoshima

研究成果: ジャーナルへの寄稿記事

抄録

Core-shell polymer-silica hybrid nanoparticles smaller than 50 nm in diameter were formed in the presence of micelles of poly(2-aminoethyl vinyl ether-block-isobutyl vinyl ether) (poly(AEVEm-b-IBVEn)) through the hydrolysis and polycondensation of alkoxysilane in aqueous solution at a mild pH and temperature. The size of the nanoparticles as well as the number and size of the core parts were effectively controlled by varying the molecular weight of the copolymers. The polymers could be removed by calcination to give hollow silica nanoparticles with Brunauer-Emmett-Teller surface areas of more than 500 m2 g-1. Among these, silica nanoparticles formed with poly(AEVE115-b-IBVE40) displayed an anisotropy of single openings in the shell. The use of an alternative copolymer, poly(AEVE-b-2-naphthoxyethyl vinyl ether) (poly(AEVE113-b-βNpOVE40)), yielded core-shell nanoparticles with less pronounced anisotropy. These results showed that the degree of anisotropy could be controlled by the rigidity of micelles; the micelle of poly(AEVE115-b-IBVE40) was more deformable during silica deposition than that of poly(AEVE113-b-βNpOVE40) in which aromatic interactions were possible. This bioinspired, environmentally friendly approach will enable large-scale production of anisotropic silica nanomaterials, opening up applications in the field of nanomedicine, optical materials, and self-assembly.

元の言語英語
ページ(範囲)10846-10854
ページ数9
ジャーナルLangmuir
35
発行部数33
DOI
出版物ステータス出版済み - 8 20 2019

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Silicon Dioxide
Amines
Ethers
ethers
amines
Anisotropy
Silica
Nanoparticles
silicon dioxide
Micelles
nanoparticles
anisotropy
synthesis
micelles
copolymers
Polymers
Copolymers
Medical nanotechnology
Optical materials
polymers

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

これを引用

Bioinspired Approach to Silica Nanoparticle Synthesis Using Amine-Containing Block Copoly(vinyl ethers) : Realizing Controlled Anisotropy. / Sugawara-Narutaki, Ayae; Tsuboike, Sachio; Oda, Yukari; Shimojima, Atsushi; Landenberger, Kira B.; Okubo, Tatsuya; Aoshima, Sadahito.

:: Langmuir, 巻 35, 番号 33, 20.08.2019, p. 10846-10854.

研究成果: ジャーナルへの寄稿記事

Sugawara-Narutaki, A, Tsuboike, S, Oda, Y, Shimojima, A, Landenberger, KB, Okubo, T & Aoshima, S 2019, 'Bioinspired Approach to Silica Nanoparticle Synthesis Using Amine-Containing Block Copoly(vinyl ethers): Realizing Controlled Anisotropy', Langmuir, 巻. 35, 番号 33, pp. 10846-10854. https://doi.org/10.1021/acs.langmuir.9b01493
Sugawara-Narutaki, Ayae ; Tsuboike, Sachio ; Oda, Yukari ; Shimojima, Atsushi ; Landenberger, Kira B. ; Okubo, Tatsuya ; Aoshima, Sadahito. / Bioinspired Approach to Silica Nanoparticle Synthesis Using Amine-Containing Block Copoly(vinyl ethers) : Realizing Controlled Anisotropy. :: Langmuir. 2019 ; 巻 35, 番号 33. pp. 10846-10854.
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abstract = "Core-shell polymer-silica hybrid nanoparticles smaller than 50 nm in diameter were formed in the presence of micelles of poly(2-aminoethyl vinyl ether-block-isobutyl vinyl ether) (poly(AEVEm-b-IBVEn)) through the hydrolysis and polycondensation of alkoxysilane in aqueous solution at a mild pH and temperature. The size of the nanoparticles as well as the number and size of the core parts were effectively controlled by varying the molecular weight of the copolymers. The polymers could be removed by calcination to give hollow silica nanoparticles with Brunauer-Emmett-Teller surface areas of more than 500 m2 g-1. Among these, silica nanoparticles formed with poly(AEVE115-b-IBVE40) displayed an anisotropy of single openings in the shell. The use of an alternative copolymer, poly(AEVE-b-2-naphthoxyethyl vinyl ether) (poly(AEVE113-b-βNpOVE40)), yielded core-shell nanoparticles with less pronounced anisotropy. These results showed that the degree of anisotropy could be controlled by the rigidity of micelles; the micelle of poly(AEVE115-b-IBVE40) was more deformable during silica deposition than that of poly(AEVE113-b-βNpOVE40) in which aromatic interactions were possible. This bioinspired, environmentally friendly approach will enable large-scale production of anisotropic silica nanomaterials, opening up applications in the field of nanomedicine, optical materials, and self-assembly.",
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