Bioinspired catalytic reactions with vitamin B12 derivative and photosensitizers

Yoshio Hisaeda, Keishiro Tahara, Hisashi Shimakoshi, Takahiro Masuko

    研究成果: Contribution to journalArticle査読

    18 被引用数 (Scopus)

    抄録

    As part of a study directed toward design of good catalytic systems based upon a hydrophobic vitamin B12, heptamethyl cobyrinate perchlorate, we describe the preparation of various nanomaterials using the vitamin B12 derivative and photosensitizers. Examples include vitamin B12-hyperbranched polymers (HBPs), human serum albumin (HSA) containing vitamin B12 derivatives, a vitamin B12-titanium dioxide hybrid catalyst, a vitamin B12-Ru complex combined system, and a vitamin B12-rose bengal combined system. These bioinspired materials have the potential as catalytic systems for the degradation of organic halide pollutants and for molecular transformations via radical intermediates during irradiation by UV or visible light, and offer a variety of applications that are of great interest in terms of green chemistry.

    本文言語英語
    ページ(範囲)1415-1426
    ページ数12
    ジャーナルPure and Applied Chemistry
    85
    7
    DOI
    出版ステータス出版済み - 2013

    All Science Journal Classification (ASJC) codes

    • 化学 (全般)
    • 化学工学(全般)

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