Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate: A head-to-tail isomer

Ken Sakai; Yoshimi Yokoyama; Hideki Hama; Kaoru Kato; Yoshie Lkuta; Taro Tsubomura; Tomoaki Tanase

doi:10.1107/S1600536804009523

Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate: A head-to-tail isomer

Ken Sakai, Yoshimi Yokoyama, Hideki Hama, Kaoru Kato, Yoshie Lkuta, Taro Tsubomura, Tomoaki Tanase

研究成果: ジャーナルへの寄稿 › 記事

5 引用（Scopus）

抜粋

In the title compound, [Pt₂(μ-C₁₄H ₁₆N₃)₄](ClO₄)₆·- 2H₂O, the diplatinum(II) cation is found to be a head-to-tail isomer. The intradimer Pt-Pt distance [3.0304 (7) Å] is much shorter than the value of 3.0852 (13) Å reported for the analogous cis-diammineplatinum(II) dimer bridged by 2-(N′-methyl-4,4′-bipyridinium-1-yl)acetamidates [Sakai, Ikuta, Tsubomura, Kato, Yokoyama, Kajiwara & Ito (2003). Acta Cry st. E59, m780-m783], showing that the electron density at the metal centers is higher in the title system than in the previously reported system. The shortest interdimer Pt⋯Pt distance is 8.4585 (8) Å.

元の言語	英語
ページ（範囲）	m664-m667
ジャーナル	Acta Crystallographica Section E: Structure Reports Online
巻	60
発行部数	5
DOI	https://doi.org/10.1107/S1600536804009523
出版物ステータス	出版済み - 5 1 2004
外部発表	Yes

フィンガープリント

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

これを引用

Sakai, K., Yokoyama, Y., Hama, H., Kato, K., Lkuta, Y., Tsubomura, T., & Tanase, T. (2004). Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate: A head-to-tail isomer. Acta Crystallographica Section E: Structure Reports Online, 60(5), m664-m667. https://doi.org/10.1107/S1600536804009523

Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate : A head-to-tail isomer. / Sakai, Ken; Yokoyama, Yoshimi; Hama, Hideki; Kato, Kaoru; Lkuta, Yoshie; Tsubomura, Taro; Tanase, Tomoaki.

：: Acta Crystallographica Section E: Structure Reports Online, 巻 60, 番号 5, 01.05.2004, p. m664-m667.

研究成果: ジャーナルへの寄稿 › 記事

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title = "Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate: A head-to-tail isomer",

abstract = "In the title compound, [Pt2(μ-C14H 16N3)4](ClO4)6·- 2H2O, the diplatinum(II) cation is found to be a head-to-tail isomer. The intradimer Pt-Pt distance [3.0304 (7) {\AA}] is much shorter than the value of 3.0852 (13) {\AA} reported for the analogous cis-diammineplatinum(II) dimer bridged by 2-(N′-methyl-4,4′-bipyridinium-1-yl)acetamidates [Sakai, Ikuta, Tsubomura, Kato, Yokoyama, Kajiwara & Ito (2003). Acta Cry st. E59, m780-m783], showing that the electron density at the metal centers is higher in the title system than in the previously reported system. The shortest interdimer Pt⋯Pt distance is 8.4585 (8) {\AA}.",

author = "Ken Sakai and Yoshimi Yokoyama and Hideki Hama and Kaoru Kato and Yoshie Lkuta and Taro Tsubomura and Tomoaki Tanase",

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T2 - A head-to-tail isomer

AU - Sakai, Ken

AU - Yokoyama, Yoshimi

AU - Hama, Hideki

AU - Kato, Kaoru

AU - Lkuta, Yoshie

AU - Tsubomura, Taro

AU - Tanase, Tomoaki

PY - 2004/5/1

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N2 - In the title compound, [Pt2(μ-C14H 16N3)4](ClO4)6·- 2H2O, the diplatinum(II) cation is found to be a head-to-tail isomer. The intradimer Pt-Pt distance [3.0304 (7) Å] is much shorter than the value of 3.0852 (13) Å reported for the analogous cis-diammineplatinum(II) dimer bridged by 2-(N′-methyl-4,4′-bipyridinium-1-yl)acetamidates [Sakai, Ikuta, Tsubomura, Kato, Yokoyama, Kajiwara & Ito (2003). Acta Cry st. E59, m780-m783], showing that the electron density at the metal centers is higher in the title system than in the previously reported system. The shortest interdimer Pt⋯Pt distance is 8.4585 (8) Å.

AB - In the title compound, [Pt2(μ-C14H 16N3)4](ClO4)6·- 2H2O, the diplatinum(II) cation is found to be a head-to-tail isomer. The intradimer Pt-Pt distance [3.0304 (7) Å] is much shorter than the value of 3.0852 (13) Å reported for the analogous cis-diammineplatinum(II) dimer bridged by 2-(N′-methyl-4,4′-bipyridinium-1-yl)acetamidates [Sakai, Ikuta, Tsubomura, Kato, Yokoyama, Kajiwara & Ito (2003). Acta Cry st. E59, m780-m783], showing that the electron density at the metal centers is higher in the title system than in the previously reported system. The shortest interdimer Pt⋯Pt distance is 8.4585 (8) Å.

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文献にアクセス

10.1107/S1600536804009523