Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate: A head-to-tail isomer

Ken Sakai; Yoshimi Yokoyama; Hideki Hama; Kaoru Kato; Yoshie Lkuta; Taro Tsubomura; Tomoaki Tanase

doi:10.1107/S1600536804009523

Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate: A head-to-tail isomer

Ken Sakai, Yoshimi Yokoyama, Hideki Hama, Kaoru Kato, Yoshie Lkuta, Taro Tsubomura, Tomoaki Tanase

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

5 被引用数 (Scopus)

抄録

In the title compound, [Pt₂(μ-C₁₄H ₁₆N₃)₄](ClO₄)₆·- 2H₂O, the diplatinum(II) cation is found to be a head-to-tail isomer. The intradimer Pt-Pt distance [3.0304 (7) Å] is much shorter than the value of 3.0852 (13) Å reported for the analogous cis-diammineplatinum(II) dimer bridged by 2-(N′-methyl-4,4′-bipyridinium-1-yl)acetamidates [Sakai, Ikuta, Tsubomura, Kato, Yokoyama, Kajiwara & Ito (2003). Acta Cry st. E59, m780-m783], showing that the electron density at the metal centers is higher in the title system than in the previously reported system. The shortest interdimer Pt⋯Pt distance is 8.4585 (8) Å.

本文言語	英語
ページ（範囲）	m664-m667
ジャーナル	Acta Crystallographica Section E: Structure Reports Online
巻	60
号	5
DOI	https://doi.org/10.1107/S1600536804009523
出版ステータス	出版済み - 5月 2004
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

化学 (全般)
材料科学（全般）
凝縮系物理学

文献へのアクセス

10.1107/S1600536804009523

他のファイルとリンク

フィンガープリント

「Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate: A head-to-tail isomer」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate : A head-to-tail isomer. / Sakai, Ken; Yokoyama, Yoshimi; Hama, Hideki その他.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 5, 05.2004, p. m664-m667.

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

@article{6ab8c79a010442c9af54fbe201ad8de6,

title = "Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate: A head-to-tail isomer",

abstract = "In the title compound, [Pt2(μ-C14H 16N3)4](ClO4)6·- 2H2O, the diplatinum(II) cation is found to be a head-to-tail isomer. The intradimer Pt-Pt distance [3.0304 (7) {\AA}] is much shorter than the value of 3.0852 (13) {\AA} reported for the analogous cis-diammineplatinum(II) dimer bridged by 2-(N′-methyl-4,4′-bipyridinium-1-yl)acetamidates [Sakai, Ikuta, Tsubomura, Kato, Yokoyama, Kajiwara & Ito (2003). Acta Cry st. E59, m780-m783], showing that the electron density at the metal centers is higher in the title system than in the previously reported system. The shortest interdimer Pt⋯Pt distance is 8.4585 (8) {\AA}.",

author = "Ken Sakai and Yoshimi Yokoyama and Hideki Hama and Kaoru Kato and Yoshie Lkuta and Taro Tsubomura and Tomoaki Tanase",

year = "2004",

month = may,

doi = "10.1107/S1600536804009523",

language = "English",

volume = "60",

pages = "m664--m667",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "5",

}

TY - JOUR

T1 - Bis[μ-3-(N′-methyl-4,4′-bipyridinium-1-yl)propionamidato] bis[cis-diammine-platinum(II)] hexaperchlorate dihydrate

T2 - A head-to-tail isomer

AU - Sakai, Ken

AU - Yokoyama, Yoshimi

AU - Hama, Hideki

AU - Kato, Kaoru

AU - Lkuta, Yoshie

AU - Tsubomura, Taro

AU - Tanase, Tomoaki

PY - 2004/5

Y1 - 2004/5

N2 - In the title compound, [Pt2(μ-C14H 16N3)4](ClO4)6·- 2H2O, the diplatinum(II) cation is found to be a head-to-tail isomer. The intradimer Pt-Pt distance [3.0304 (7) Å] is much shorter than the value of 3.0852 (13) Å reported for the analogous cis-diammineplatinum(II) dimer bridged by 2-(N′-methyl-4,4′-bipyridinium-1-yl)acetamidates [Sakai, Ikuta, Tsubomura, Kato, Yokoyama, Kajiwara & Ito (2003). Acta Cry st. E59, m780-m783], showing that the electron density at the metal centers is higher in the title system than in the previously reported system. The shortest interdimer Pt⋯Pt distance is 8.4585 (8) Å.

AB - In the title compound, [Pt2(μ-C14H 16N3)4](ClO4)6·- 2H2O, the diplatinum(II) cation is found to be a head-to-tail isomer. The intradimer Pt-Pt distance [3.0304 (7) Å] is much shorter than the value of 3.0852 (13) Å reported for the analogous cis-diammineplatinum(II) dimer bridged by 2-(N′-methyl-4,4′-bipyridinium-1-yl)acetamidates [Sakai, Ikuta, Tsubomura, Kato, Yokoyama, Kajiwara & Ito (2003). Acta Cry st. E59, m780-m783], showing that the electron density at the metal centers is higher in the title system than in the previously reported system. The shortest interdimer Pt⋯Pt distance is 8.4585 (8) Å.

UR - http://www.scopus.com/inward/record.url?scp=18444404023&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=18444404023&partnerID=8YFLogxK

U2 - 10.1107/S1600536804009523

DO - 10.1107/S1600536804009523

M3 - Article

AN - SCOPUS:18444404023

VL - 60

SP - m664-m667

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 5

ER -