Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ 4 N]iron(II)

Jing Wei Dai, Zhao Yang Li, Osamu Sato

研究成果: ジャーナルへの寄稿記事

1 引用 (Scopus)

抄録

In the title complex, [Fe(NCS)2(C18H18N4)], the Fe II cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å 3 , which are free of solvent molecules.

元の言語英語
ジャーナルActa Crystallographica Section E: Structure Reports Online
70
発行部数2
DOI
出版物ステータス出版済み - 2 1 2014

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Amines
amines
Iron
iron
centroids
Molecules
molecules
Pyridine
Anions
Cations
voids
pyridines
Hydrogen bonds
Negative ions
Positive ions
Ligands
hydrogen bonds
anions
cations
Crystals

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

これを引用

Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ 4 N]iron(II) . / Dai, Jing Wei; Li, Zhao Yang; Sato, Osamu.

:: Acta Crystallographica Section E: Structure Reports Online, 巻 70, 番号 2, 01.02.2014.

研究成果: ジャーナルへの寄稿記事

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abstract = "In the title complex, [Fe(NCS)2(C18H18N4)], the Fe II cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3){\AA}] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9){\AA} 3 , which are free of solvent molecules.",
author = "Dai, {Jing Wei} and Li, {Zhao Yang} and Osamu Sato",
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AU - Li, Zhao Yang

AU - Sato, Osamu

PY - 2014/2/1

Y1 - 2014/2/1

N2 - In the title complex, [Fe(NCS)2(C18H18N4)], the Fe II cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å 3 , which are free of solvent molecules.

AB - In the title complex, [Fe(NCS)2(C18H18N4)], the Fe II cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C - HS hydrogen bonds and π-π stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653(3)Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124(9)Å 3 , which are free of solvent molecules.

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