Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W

Daiya Kobayashi; Hirokazu Kobayashi; Kohei Kusada; Tomokazu Yamamoto; Takaaki Toriyama; Syo Matsumura; Shogo Kawaguchi; Yoshiki Kubota; Masaaki Haneda; Susan Meñez Aspera; Hiroshi Nakanishi; Shigebumi Arai; Hiroshi Kitagawa

doi:10.1039/d1ta03480d

Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W

Daiya Kobayashi, Hirokazu Kobayashi, Kohei Kusada, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Shogo Kawaguchi, Yoshiki Kubota, Masaaki Haneda, Susan Meñez Aspera, Hiroshi Nakanishi, Shigebumi Arai, Hiroshi Kitagawa

研究成果: Contribution to journal › Article › 査読

1 被引用数 (Scopus)

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The reverse water-gas shift (RWGS) reaction is an important reaction from the viewpoint of converting CO₂into CO as an important raw material compound. As the RWGS reaction is a mildly endothermic and competitive reaction with CO₂methanation, it is important to improve the activity at low temperatures. Here, we report PtW nanoparticles (NPs) supported on γ-Al₂O₃(PtW NPs/Al₂O₃) in which Pt and W were randomly mixed for obtaining a highly active and selective catalyst for the RWGS. At low temperatures of 200 and 300 °C, PtW NPs/Al₂O₃exhibited 16- and 17-times higher activity than Pt/Al₂O₃, one of the most promising catalysts. The enhanced activity of PtW NPs originated from alloying Pt with W, which contributes to the sintering resistance of Pt NPs, and promotion of CO₂adsorption and CO desorption on the catalyst. Furthermore, PtW NPs/Al₂O₃exhibited high durability and excellent catalytic performance.

本文言語	英語
ページ（範囲）	15613-15617
ページ数	5
ジャーナル	Journal of Materials Chemistry A
巻	9
号	28
DOI	https://doi.org/10.1039/d1ta03480d
出版ステータス	出版済み - 7 28 2021

All Science Journal Classification (ASJC) codes

化学 (全般)
再生可能エネルギー、持続可能性、環境
材料科学（全般）

UN SDG

この成果は、次の持続可能な開発目標に貢献しています

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10.1039/d1ta03480d

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引用スタイル

Kobayashi, D., Kobayashi, H., Kusada, K., Yamamoto, T., Toriyama, T., Matsumura, S., Kawaguchi, S., Kubota, Y., Haneda, M., Aspera, S. M., Nakanishi, H., Arai, S., & Kitagawa, H. (2021). Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W. Journal of Materials Chemistry A, 9(28), 15613-15617. https://doi.org/10.1039/d1ta03480d

Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W. / Kobayashi, Daiya; Kobayashi, Hirokazu; Kusada, Kohei; Yamamoto, Tomokazu; Toriyama, Takaaki; Matsumura, Syo; Kawaguchi, Shogo; Kubota, Yoshiki; Haneda, Masaaki; Aspera, Susan Meñez; Nakanishi, Hiroshi; Arai, Shigebumi; Kitagawa, Hiroshi.

In: Journal of Materials Chemistry A, Vol. 9, No. 28, 28.07.2021, p. 15613-15617.

研究成果: Contribution to journal › Article › 査読

Kobayashi, D, Kobayashi, H, Kusada, K, Yamamoto, T, Toriyama, T, Matsumura, S, Kawaguchi, S, Kubota, Y, Haneda, M, Aspera, SM, Nakanishi, H, Arai, S & Kitagawa, H 2021, 'Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W', Journal of Materials Chemistry A, vol. 9, no. 28, pp. 15613-15617. https://doi.org/10.1039/d1ta03480d

Kobayashi, Daiya ; Kobayashi, Hirokazu ; Kusada, Kohei ; Yamamoto, Tomokazu ; Toriyama, Takaaki ; Matsumura, Syo ; Kawaguchi, Shogo ; Kubota, Yoshiki ; Haneda, Masaaki ; Aspera, Susan Meñez ; Nakanishi, Hiroshi ; Arai, Shigebumi ; Kitagawa, Hiroshi. / Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W. In: Journal of Materials Chemistry A. 2021 ; Vol. 9, No. 28. pp. 15613-15617.

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title = "Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W",

abstract = "The reverse water-gas shift (RWGS) reaction is an important reaction from the viewpoint of converting CO2into CO as an important raw material compound. As the RWGS reaction is a mildly endothermic and competitive reaction with CO2methanation, it is important to improve the activity at low temperatures. Here, we report PtW nanoparticles (NPs) supported on γ-Al2O3(PtW NPs/Al2O3) in which Pt and W were randomly mixed for obtaining a highly active and selective catalyst for the RWGS. At low temperatures of 200 and 300 °C, PtW NPs/Al2O3exhibited 16- and 17-times higher activity than Pt/Al2O3, one of the most promising catalysts. The enhanced activity of PtW NPs originated from alloying Pt with W, which contributes to the sintering resistance of Pt NPs, and promotion of CO2adsorption and CO desorption on the catalyst. Furthermore, PtW NPs/Al2O3exhibited high durability and excellent catalytic performance.",

author = "Daiya Kobayashi and Hirokazu Kobayashi and Kohei Kusada and Tomokazu Yamamoto and Takaaki Toriyama and Syo Matsumura and Shogo Kawaguchi and Yoshiki Kubota and Masaaki Haneda and Aspera, {Susan Me{\~n}ez} and Hiroshi Nakanishi and Shigebumi Arai and Hiroshi Kitagawa",

note = "Funding Information: This work was partly supported by Advanced Characterization Platform of the Nanotechnology Platform Japan (JPMXP09-A-19-KU-0292) sponsored by the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan. The synchrotron radiation experiments were performed at the BL02B2 of SPring-8 with the approval of JASRI (Proposal No. 2018A1376, 2018B1501, 2019A1232, 2019B1468). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

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doi = "10.1039/d1ta03480d",

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AU - Kobayashi, Daiya

AU - Kobayashi, Hirokazu

AU - Kusada, Kohei

AU - Yamamoto, Tomokazu

AU - Toriyama, Takaaki

AU - Matsumura, Syo

AU - Kawaguchi, Shogo

AU - Kubota, Yoshiki

AU - Haneda, Masaaki

AU - Aspera, Susan Meñez

AU - Nakanishi, Hiroshi

AU - Arai, Shigebumi

AU - Kitagawa, Hiroshi

N1 - Funding Information: This work was partly supported by Advanced Characterization Platform of the Nanotechnology Platform Japan (JPMXP09-A-19-KU-0292) sponsored by the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan. The synchrotron radiation experiments were performed at the BL02B2 of SPring-8 with the approval of JASRI (Proposal No. 2018A1376, 2018B1501, 2019A1232, 2019B1468). Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/7/28

Y1 - 2021/7/28

N2 - The reverse water-gas shift (RWGS) reaction is an important reaction from the viewpoint of converting CO2into CO as an important raw material compound. As the RWGS reaction is a mildly endothermic and competitive reaction with CO2methanation, it is important to improve the activity at low temperatures. Here, we report PtW nanoparticles (NPs) supported on γ-Al2O3(PtW NPs/Al2O3) in which Pt and W were randomly mixed for obtaining a highly active and selective catalyst for the RWGS. At low temperatures of 200 and 300 °C, PtW NPs/Al2O3exhibited 16- and 17-times higher activity than Pt/Al2O3, one of the most promising catalysts. The enhanced activity of PtW NPs originated from alloying Pt with W, which contributes to the sintering resistance of Pt NPs, and promotion of CO2adsorption and CO desorption on the catalyst. Furthermore, PtW NPs/Al2O3exhibited high durability and excellent catalytic performance.

AB - The reverse water-gas shift (RWGS) reaction is an important reaction from the viewpoint of converting CO2into CO as an important raw material compound. As the RWGS reaction is a mildly endothermic and competitive reaction with CO2methanation, it is important to improve the activity at low temperatures. Here, we report PtW nanoparticles (NPs) supported on γ-Al2O3(PtW NPs/Al2O3) in which Pt and W were randomly mixed for obtaining a highly active and selective catalyst for the RWGS. At low temperatures of 200 and 300 °C, PtW NPs/Al2O3exhibited 16- and 17-times higher activity than Pt/Al2O3, one of the most promising catalysts. The enhanced activity of PtW NPs originated from alloying Pt with W, which contributes to the sintering resistance of Pt NPs, and promotion of CO2adsorption and CO desorption on the catalyst. Furthermore, PtW NPs/Al2O3exhibited high durability and excellent catalytic performance.

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Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W

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All Science Journal Classification (ASJC) codes

UN SDG

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