Boron Difluoride Complexes of Expanded N-Confused Calix[n]phyrins That Demonstrate Unique Luminescent and Lasing Properties

Masatoshi Ishida, Toshihiro Omagari, Ryuji Hirosawa, Keisuke Jono, Young Mo Sung, Yuhsuke Yasutake, Hidemitsu Uno, Motoki Toganoh, Hajime Nakanotani, Susumu Fukatsu, Dongho Kim, Hiroyuki Furuta

研究成果: ジャーナルへの寄稿記事

13 引用 (Scopus)

抄録

Complexation of novel multiply N-confused expanded calix[n]phyrins with boron difluoride afforded a new class of cyclic BODIPY (boron-dipyrromethene) arrays. The structures of circularly arranged BODIPY subunits linked in an N-confused fashion give rise to such photophysical properties unique to the macrocycles as redshifted emission wavelengths along with apparent large Stokes shifts, long emission lifetimes, and solid-state lasing. The DFT calculations support the size-dependent excited-state dynamics of the macrocycles.

元の言語英語
ページ(範囲)12045-12049
ページ数5
ジャーナルAngewandte Chemie - International Edition
55
発行部数39
DOI
出版物ステータス出版済み - 1 1 2016

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Boron
Complexation
Excited states
Discrete Fourier transforms
Wavelength
dipyrromethene
boron difluoride

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

これを引用

Boron Difluoride Complexes of Expanded N-Confused Calix[n]phyrins That Demonstrate Unique Luminescent and Lasing Properties. / Ishida, Masatoshi; Omagari, Toshihiro; Hirosawa, Ryuji; Jono, Keisuke; Sung, Young Mo; Yasutake, Yuhsuke; Uno, Hidemitsu; Toganoh, Motoki; Nakanotani, Hajime; Fukatsu, Susumu; Kim, Dongho; Furuta, Hiroyuki.

:: Angewandte Chemie - International Edition, 巻 55, 番号 39, 01.01.2016, p. 12045-12049.

研究成果: ジャーナルへの寄稿記事

Ishida, Masatoshi ; Omagari, Toshihiro ; Hirosawa, Ryuji ; Jono, Keisuke ; Sung, Young Mo ; Yasutake, Yuhsuke ; Uno, Hidemitsu ; Toganoh, Motoki ; Nakanotani, Hajime ; Fukatsu, Susumu ; Kim, Dongho ; Furuta, Hiroyuki. / Boron Difluoride Complexes of Expanded N-Confused Calix[n]phyrins That Demonstrate Unique Luminescent and Lasing Properties. :: Angewandte Chemie - International Edition. 2016 ; 巻 55, 番号 39. pp. 12045-12049.
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AU - Omagari, Toshihiro

AU - Hirosawa, Ryuji

AU - Jono, Keisuke

AU - Sung, Young Mo

AU - Yasutake, Yuhsuke

AU - Uno, Hidemitsu

AU - Toganoh, Motoki

AU - Nakanotani, Hajime

AU - Fukatsu, Susumu

AU - Kim, Dongho

AU - Furuta, Hiroyuki

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