TY - JOUR
T1 - C-H Bond Functionalization Using Pd- And Au-Supported Catalysts with Mechanistic Insights of the Active Species
AU - Ishida, Tamao
AU - Zhang, Zhenzhong
AU - Murayama, Haruno
AU - Yamamoto, Eiji
AU - Tokunaga, Makoto
N1 - Funding Information:
This work was financially supported by a Grant-in-Aid for Scientific Research (B) (Grant no. 19H02755) from the Ministry of Education, Culture, Science, Sports and Technology, Japan, and by the Japan Society for the Promotion of Science (JSPS) and National Natural Science Foundation of China (NSFC) under the Joint Research Program (JRP with NSFC, Grant no. JPJSJRP 20191804). JapanSocietyforthePomotionofScience19H02755)MinistyofEducaion, Cultue, Science, SpotsandTechnology, Japan(19H02755)Natonal Naural ScienceFoundaionofChina()
Publisher Copyright:
© 2021 Georg Thieme Verlag. All rights reserved.
PY - 2021/9/16
Y1 - 2021/9/16
N2 - The process of C-H functionalization has been extensively studied as a direct C-C bond-forming reaction with high atomic efficiency. Efforts have also been made on such reactions by using supported catalysts, which are superior in terms of catalyst separation from the reaction mixture and reusability. In this review, an overview of C-H functionalization reactions, especially those involving Pd- and Au-supported catalysts, is presented. In particular, we discuss reaction mechanisms, active species, leaching, reusability, etc. 1 Introduction 2 Types of Supported Metal Catalysts and Their Active Species 3 Modes of C-H Bond Activation 4 Oxidative C-H C-H Coupling of Aryl Compounds 5 C-H C-H Coupling Where One Side Is Aromatic 6 C-H Acylation of Aromatic Compounds and Related Reactions 7 Conclusion.
AB - The process of C-H functionalization has been extensively studied as a direct C-C bond-forming reaction with high atomic efficiency. Efforts have also been made on such reactions by using supported catalysts, which are superior in terms of catalyst separation from the reaction mixture and reusability. In this review, an overview of C-H functionalization reactions, especially those involving Pd- and Au-supported catalysts, is presented. In particular, we discuss reaction mechanisms, active species, leaching, reusability, etc. 1 Introduction 2 Types of Supported Metal Catalysts and Their Active Species 3 Modes of C-H Bond Activation 4 Oxidative C-H C-H Coupling of Aryl Compounds 5 C-H C-H Coupling Where One Side Is Aromatic 6 C-H Acylation of Aromatic Compounds and Related Reactions 7 Conclusion.
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U2 - 10.1055/a-1468-1455
DO - 10.1055/a-1468-1455
M3 - Article
AN - SCOPUS:85105116255
SN - 0039-7881
VL - 53
SP - 3279
EP - 3289
JO - Synthesis
JF - Synthesis
IS - 18
ER -