Carrier transport properties of monodisperse glassy-nematic oligofluorenes in organic field-effect transistors

Takeshi Yasuda, Katsuhiko Fujita, Tetsuo Tsutsui, Yanhou Geng, Sean W. Culligan, Shaw H. Chen

研究成果: ジャーナルへの寄稿学術誌査読

114 被引用数 (Scopus)

抄録

A heptafluorene, F(Pr)5F(MB)2, a dodecafluorene, F(MB)10F(EH)2, and poly(9,9′-dioctylfluorene), PFO, were used to prepare field-effect transistors. Monodomain and polydomain glassy-nematic films as well as glassy-amorphous films were prepared for the measurement of hole mobility. In a monodomain film, the μ value is determined by the chain length in oligofluorene and the persistence length in polyfluorene. Mobility in a polydomain film lies between μ and μ of a monodomain film. Amorphous films possess the lowest mobility of all presumably because of the geometric and energetic disorder. The OFET containing a monodomain glassy-nematic film of F(MB) 10F(EH)2 exhibits a field-effect mobility of 0.012 cm2/Vs with an on/off current ratio of 1.0 × 104, a substantial improvement over a monodomain glassy-nematic film of PFO.

本文言語英語
ページ(範囲)264-268
ページ数5
ジャーナルChemistry of Materials
17
2
DOI
出版ステータス出版済み - 1月 25 2005

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 化学工学(全般)
  • 材料化学

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