Catalytic Asymmetric Hydrogenation of Heteroarenes and Arenes

研究成果: ジャーナルへの寄稿記事

2 引用 (Scopus)

抄録

A trans-chelating chiral bisphosphine, PhTRAP, allows the ruthenium-catalyzed hydrogenation of various azoles to proceed with high enantioselectivity. The PhTRAP-ruthenium catalyst transformed indoles, pyrroles, imidazoles, and oxazoles into the corresponding chiral heterocycles. Naphthalenes are also reduced with hydrogen by the chiral ruthenium catalyst, exclusively giving tetralins. Some 2-alkoxytetralins were obtained with over 90% ee from the catalytic asymmetric hydrogenation of the corresponding substituted naphthalenes.

元の言語英語
ページ(範囲)715-719
ページ数5
ジャーナルPhosphorus, Sulfur and Silicon and the Related Elements
190
発行部数5-6
DOI
出版物ステータス出版済み - 6 3 2015

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Hydrogenation
Ruthenium
Naphthalenes
Tetrahydronaphthalenes
Oxazoles
Imidazoles
Indoles
Azoles
Catalysts
Pyrroles
Enantioselectivity
Chelation
Hydrogen

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

これを引用

Catalytic Asymmetric Hydrogenation of Heteroarenes and Arenes. / Kuwano, Ryoichi.

:: Phosphorus, Sulfur and Silicon and the Related Elements, 巻 190, 番号 5-6, 03.06.2015, p. 715-719.

研究成果: ジャーナルへの寄稿記事

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