Catalytic asymmetric hydrogenation of naphthalenes

Ryoichi Kuwano; Ryuichi Morioka; Manabu Kashiwabara; Nao Kameyama

doi:10.1002/anie.201201153

Catalytic asymmetric hydrogenation of naphthalenes

Ryoichi Kuwano, Ryuichi Morioka, Manabu Kashiwabara, Nao Kameyama

複合領域化学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

58 被引用数 (Scopus)

抄録

Vanishing aromaticity: A chiral ruthenium complex catalyzes the hydrogenation of 2,6- or 2,7-disubstituted naphthalenes to give chiral tetralins with up to 92 % ee. The chiral catalyst is applicable to the regio- and enantioselective reduction of 6-substituted 2-alkoxynaphthalenes and preferentially hydrogenates the alkoxy-substituted arene rings.

本文言語	英語
ページ（範囲）	4136-4139
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	51
号	17
DOI	https://doi.org/10.1002/anie.201201153
出版ステータス	出版済み - 4月 23 2012

All Science Journal Classification (ASJC) codes

触媒
化学 (全般)

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10.1002/anie.201201153

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Catalytic asymmetric hydrogenation of naphthalenes

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