Catalytic C-F bond hydrogenolysis of fluoroaromatics by [(η5-C5Me5)RhI(2,2′-bipyridine)]

Hidetaka Nakai, Kihun Jeong, Takahiro Matsumoto, Seiji Ogo

研究成果: Contribution to journalArticle査読

30 被引用数 (Scopus)

抄録

A new class of efficient catalyst, the Rh(I) complex [(η5-C5Me5)RhI(bpy)] (1; bpy = 2,2′-bipyridine), for the C-F bond hydrogenolysis of fluoroaromatics (C6F5CF3, C6F6, C6F5H, and C6F5CH3) is presented. The best turnover number of 380 for C6F6 is afforded by using 0.1 mol % of 1, 0.8 MPa of H2, and 2 equiv of Et2NH in CH3CN at 25 °C. The successful isolation of the C-F bond cleavage product [(η5-C5Me5)RhIII(bpy)(C6F5)](F) as a plausible intermediate of the catalytic hydrogenolysis of C6F6 by 1 is also described.

本文言語英語
ページ(範囲)4349-4352
ページ数4
ジャーナルOrganometallics
33
17
DOI
出版ステータス出版済み - 9 8 2014

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

フィンガープリント 「Catalytic C-F bond hydrogenolysis of fluoroaromatics by [(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Rh<sup>I</sup>(2,2′-bipyridine)]」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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