Catalytic decomposition of CFCs

Yusaku Takita, Tatsumi Ishihara

研究成果: ジャーナルへの寄稿学術誌査読

30 被引用数 (Scopus)

抄録

Catalytic decomposition of CCl2F2 was studied over a number of single and complex metal oxides using a fixed-bed reactor. The ZrO2-Cr2O3 catalyst exhibited the highest activity and CO2 and CClF3 were formed at 350 450°C. Selective decomposition of CCl2F2 into CO2 required the presence of both oxygen and water vapor over the catalyst. Catalytic activity gradually declined with time on stream because of the fluorination of ZrO2. Treatment of the catalyst with both oxygen and water vapor promoted the removal of fluoride ions in sub-surface layers of the catalyst, which is effective for the recovery of the activity. CCl2F2 was decomposed at 300-450°C over AlPO4. No fluorination of the AlPO4 catalyst took place after the reaction for 1000 h. CH2FCF3, an alternative CFC, was completely decomposed over the mixed catalyst of Ce promoted AlPO4 and Cr2O3 at 400-500°C. Catalytic decomposition is a rational method for destruction of used CFCs.

本文言語英語
ページ(範囲)165-173
ページ数9
ジャーナルCatalysis Surveys from Japan
2
2
DOI
出版ステータス出版済み - 1月 1 1998
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 物理化学および理論化学

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