Catalytic enantioselective synthesis of alkenylhydrosilanes

Kazunobu Igawa, Daisuke Yoshihiro, Nobumasa Ichikawa, Naoto Kokan, Katsuhiko Tomooka

研究成果: ジャーナルへの寄稿記事

40 引用 (Scopus)

抜粋

Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.

元の言語英語
ページ(範囲)12745-12748
ページ数4
ジャーナルAngewandte Chemie - International Edition
51
発行部数51
DOI
出版物ステータス出版済み - 12 14 2012

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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