Catalytic enantioselective synthesis of alkenylhydrosilanes

Kazunobu Igawa; Daisuke Yoshihiro; Nobumasa Ichikawa; Naoto Kokan; Katsuhiko Tomooka

doi:10.1002/anie.201207361

Catalytic enantioselective synthesis of alkenylhydrosilanes

Kazunobu Igawa, Daisuke Yoshihiro, Nobumasa Ichikawa, Naoto Kokan, Katsuhiko Tomooka

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

86 被引用数 (Scopus)

抄録

Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.

本文言語	英語
ページ（範囲）	12745-12748
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	51
号	51
DOI	https://doi.org/10.1002/anie.201207361
出版ステータス	出版済み - 12月 14 2012

!!!All Science Journal Classification (ASJC) codes

触媒
化学 (全般)

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10.1002/anie.201207361

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abstract = "Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.",

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AU - Igawa, Kazunobu

AU - Yoshihiro, Daisuke

AU - Ichikawa, Nobumasa

AU - Kokan, Naoto

AU - Tomooka, Katsuhiko

PY - 2012/12/14

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N2 - Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.

AB - Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.

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Catalytic enantioselective synthesis of alkenylhydrosilanes

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!!!All Science Journal Classification (ASJC) codes

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