Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand

Masato Ito; Takashi Ootsuka; Ryo Watari; Akira Shiibashi; Akio Himizu; Takao Ikariya

doi:10.1021/ja1117254

Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand

Masato Ito, Takashi Ootsuka, Ryo Watari, Akira Shiibashi, Akio Himizu, Takao Ikariya

分子集積化学部門

研究成果: Contribution to journal › Article › 査読

161 被引用数 (Scopus)

抄録

A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.

本文言語	英語
ページ（範囲）	4240-4242
ページ数	3
ジャーナル	Journal of the American Chemical Society
巻	133
号	12
DOI	https://doi.org/10.1021/ja1117254
出版ステータス	出版済み - 3 30 2011

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

文献へのアクセス

10.1021/ja1117254

他のファイルとリンク

フィンガープリント「Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{e1d493d4f60541019259068173d8baf2,

title = "Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand",

abstract = "A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.",

author = "Masato Ito and Takashi Ootsuka and Ryo Watari and Akira Shiibashi and Akio Himizu and Takao Ikariya",

year = "2011",

month = mar,

day = "30",

doi = "10.1021/ja1117254",

language = "English",

volume = "133",

pages = "4240--4242",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand

AU - Ito, Masato

AU - Ootsuka, Takashi

AU - Watari, Ryo

AU - Shiibashi, Akira

AU - Himizu, Akio

AU - Ikariya, Takao

PY - 2011/3/30

Y1 - 2011/3/30

N2 - A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.

AB - A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.

UR - http://www.scopus.com/inward/record.url?scp=79953048472&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79953048472&partnerID=8YFLogxK

U2 - 10.1021/ja1117254

DO - 10.1021/ja1117254

M3 - Article

C2 - 21381768

AN - SCOPUS:79953048472

VL - 133

SP - 4240

EP - 4242

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 12

ER -