Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand

Masato Ito, Takashi Ootsuka, Ryo Watari, Akira Shiibashi, Akio Himizu, Takao Ikariya

研究成果: Contribution to journalArticle査読

161 被引用数 (Scopus)

抄録

A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.

本文言語英語
ページ(範囲)4240-4242
ページ数3
ジャーナルJournal of the American Chemical Society
133
12
DOI
出版ステータス出版済み - 3 30 2011

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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