Catalytic nitrogen fixation via direct cleavage of nitrogen-nitrogen triple bond of molecular dinitrogen under ambient reaction conditions

Kazuya Arashiba, Aya Eizawa, Hiromasa Tanaka, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

研究成果: ジャーナルへの寄稿記事

33 引用 (Scopus)

抄録

We have now found that molybdenumiodide complexes bearing a PNP-pincer ligand have a higher catalytic activity than the so far reported molybdenumdinitrogen complexes for ammonia formation from nitrogen gas under ambient reaction conditions, up to 830 equiv being produced based on a dinitrogen-bridged dimolybdenum complex (415 equiv of ammonia based on the molybdenum atom). This remarkable catalytic activity is induced by a novel reaction pathway, where the generation of a dinitrogen-bridged dimolybdenumiodide complex is a key point to promote direct cleavage of the nitrogennitrogen triple bond of the bridging dinitrogen ligand in the MoN τNMo core.

元の言語英語
ページ(範囲)1111-1118
ページ数8
ジャーナルBulletin of the Chemical Society of Japan
90
発行部数10
DOI
出版物ステータス出版済み - 1 1 2017

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Nitrogen fixation
Ammonia
Catalyst activity
Bearings (structural)
Nitrogen
Ligands
Molybdenum
Gases
Atoms

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

これを引用

Catalytic nitrogen fixation via direct cleavage of nitrogen-nitrogen triple bond of molecular dinitrogen under ambient reaction conditions. / Arashiba, Kazuya; Eizawa, Aya; Tanaka, Hiromasa; Nakajima, Kazunari; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki.

:: Bulletin of the Chemical Society of Japan, 巻 90, 番号 10, 01.01.2017, p. 1111-1118.

研究成果: ジャーナルへの寄稿記事

Arashiba, Kazuya ; Eizawa, Aya ; Tanaka, Hiromasa ; Nakajima, Kazunari ; Yoshizawa, Kazunari ; Nishibayashi, Yoshiaki. / Catalytic nitrogen fixation via direct cleavage of nitrogen-nitrogen triple bond of molecular dinitrogen under ambient reaction conditions. :: Bulletin of the Chemical Society of Japan. 2017 ; 巻 90, 番号 10. pp. 1111-1118.
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