Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes

Yoshiya Sekiguchi, Kazuya Arashiba, Hiromasa Tanaka, Aya Eizawa, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

研究成果: ジャーナルへの寄稿記事

23 引用 (Scopus)

抄録

Newly designed and prepared vanadium complexes bearing anionic pyrrole-based PNP-type pincer and aryloxy ligands were found to work as effective catalysts for the direct conversion of molecular dinitrogen into ammonia and hydrazine under mild reaction conditions. This is the first successful example of vanadium-catalyzed dinitrogen reduction under mild reaction conditions.

元の言語英語
ページ(範囲)9064-9068
ページ数5
ジャーナルAngewandte Chemie - International Edition
57
発行部数29
DOI
出版物ステータス出版済み - 7 16 2018

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hydrazine
Vanadium
Hydrazine
Ammonia
Bearings (structural)
Pyrroles
Ligands
Catalysts

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

これを引用

Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes. / Sekiguchi, Yoshiya; Arashiba, Kazuya; Tanaka, Hiromasa; Eizawa, Aya; Nakajima, Kazunari; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki.

:: Angewandte Chemie - International Edition, 巻 57, 番号 29, 16.07.2018, p. 9064-9068.

研究成果: ジャーナルへの寄稿記事

Sekiguchi, Y, Arashiba, K, Tanaka, H, Eizawa, A, Nakajima, K, Yoshizawa, K & Nishibayashi, Y 2018, 'Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes', Angewandte Chemie - International Edition, 巻. 57, 番号 29, pp. 9064-9068. https://doi.org/10.1002/anie.201802310
Sekiguchi, Yoshiya ; Arashiba, Kazuya ; Tanaka, Hiromasa ; Eizawa, Aya ; Nakajima, Kazunari ; Yoshizawa, Kazunari ; Nishibayashi, Yoshiaki. / Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes. :: Angewandte Chemie - International Edition. 2018 ; 巻 57, 番号 29. pp. 9064-9068.
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