Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes

Yoshiya Sekiguchi, Kazuya Arashiba, Hiromasa Tanaka, Aya Eizawa, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

研究成果: Contribution to journalArticle査読

59 被引用数 (Scopus)

抄録

Newly designed and prepared vanadium complexes bearing anionic pyrrole-based PNP-type pincer and aryloxy ligands were found to work as effective catalysts for the direct conversion of molecular dinitrogen into ammonia and hydrazine under mild reaction conditions. This is the first successful example of vanadium-catalyzed dinitrogen reduction under mild reaction conditions.

本文言語英語
ページ(範囲)9064-9068
ページ数5
ジャーナルAngewandte Chemie - International Edition
57
29
DOI
出版ステータス出版済み - 7 16 2018

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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