Catalytic transformations of benzylic carboxylates and carbonates

研究成果: ジャーナルへの寄稿評論記事

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Benzylic carboxylates and carbonates react with various molecules in the presence of homogeneous palladium or cobalt catalysts. The catalytic transformations occur at the benzylic carbons of the substrates, affording benzylic substitution products. This review surveys the catalytic reactions using benzylic carboxylates and carbonates as substrates. Furthermore, the related studies on (η3-benzyl)metal complexes are summarized in order to facilitate the understanding and consideration of the catalytic substitution. 1 Introduction 2 Chemistry of the (η3-Benzyl)metal Complex 2.1 Structure of the (η3-Benzyl)metal Complex 2.2 Reactivity of the (η3-Benzyl)metal Complex 3 Catalytic Transformations of Benzylic Esters 3.1 Nucleophilic Substitution 3.2 Cross-Coupling with Organometallic Compounds 3.3 Miscellaneous Reactions 4 Concluding Remarks.

元の言語英語
記事番号E23109SS
ページ(範囲)1049-1061
ページ数13
ジャーナルSynthesis
発行部数7
DOI
出版物ステータス出版済み - 4 1 2009

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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