CHAPTER 6: Manganese Catalysis

Y. Kuninobu, S. Sueki, N. Kaplaneris, L. Ackermann

研究成果: Chapter in Book/Report/Conference proceedingChapter

1 被引用数 (Scopus)

抄録

In this chapter, we summarize the manganese-catalysed transformations developed over the last 20 years. Because manganese is the third most abundant transition metal according to the Clarke number, the price is cheaper than that of almost any other transition metal. Therefore, the development of synthetic organic reactions using manganese catalysts is highly important and desired. In addition, several reactions, which are specific to manganese catalysts, have also been reported. This chapter describes (1) oxidation reactions (epoxidation of alkenes, C-H oxidation, and dehydrogenation); (2) reduction (of alkenes and heterocycles, alkynes, carbonyl compounds, imine derivatives, nitriles and amides, CO2 and CO, and alcohols); (3) carbon-carbon bond formation (addition to unsaturated molecules and cross-coupling reactions); (4) C-H activation (addition to C-C multiple bonds, substitutive C-H functionalization, C-H alkylation, C-H arylation, C-N bond forming reactions, and domino C-H activation reactions); and (5) others (cyclization, annulation, addition to olefins, coupling reaction, C-C bond cleavage, and various others).

本文言語英語
ホスト出版物のタイトルCatalysis with Earth-abundant Elements
編集者Uwe Schneider, Stephen Thomas
出版社Royal Society of Chemistry
ページ139-230
ページ数92
40
ISBN(電子版)9781788011181
DOI
出版ステータス出版済み - 2021

出版物シリーズ

名前RSC Catalysis Series
番号40
2021-January
ISSN(印刷版)1757-6725
ISSN(電子版)1757-6733

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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