Characterizations of interlayer organic-inorganic nanohybrid of molybdenum trioxide with polyaniline and poly(o-anisidine)

Toshio Itoh, Ichiro Matsubara, Woosuck Shin, Noriya Izu, Maiko Nishibori

研究成果: ジャーナルへの寄稿記事

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Characterizations of layered MoO3 host with interlayer polyaniline (PANI) and poly(o-anisidine) (PoANIS), i.e. (PANI)xMoO3 and (PoANIS)xMoO3, respectively, have been carried out by means of X-ray diffraction (XRD), infrared (IR) spectra, thermogravimetry (TG), and solid-state nuclear magnetic resonance (NMR) analyses. The guest organic components, i.e. PANI and PoANIS, are accommodated into MoO3 interlayers by ion-exchange process. From these detailed characterization studies, it is found that the interlayer PANI and PoANIS chains have neutralized units as well as cationic units. Moreover, the (PANI)xMoO3 and (PoANIS)xMoO3 hybrids have enough interlayer spaces due to almost perpendicular orientation of benzene ring into PANI and PoANIS chains to the MoO3 layer.

元の言語英語
ページ(範囲)115-119
ページ数5
ジャーナルMaterials Chemistry and Physics
110
発行部数1
DOI
出版物ステータス出版済み - 7 15 2008

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics

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