Charge separation on the micelle surface as evidence for a multi-step hydrogen transfer mechanism in NADH model reduction

Seiji Shinkai, Takaharu Tsuno, Osamu Manabe

研究成果: Contribution to journalArticle査読

15 被引用数 (Scopus)

抄録

Reductive desulphonation of 2,4,6-trinitrobenzenesulphonate by N-dodecyl-1 -benzyl-1,4-dihydronicotinamide bound to the sodium dodecyl sulphate micelle in D2O solution gave 1,3,5-trinitrobenzene which contained 4.6-5.1% of deuterium; the result indicates that the reaction proceeds through multi-step hydrogen transfer via a radical ion-pair intermediate and the micelle surface is capable of dissociating the radical ion pair.

本文言語英語
ページ(範囲)592-594
ページ数3
ジャーナルJournal of the Chemical Society, Chemical Communications
11
DOI
出版ステータス出版済み - 1 1 1982
外部発表はい

All Science Journal Classification (ASJC) codes

  • 分子医療

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