Chemoselective Transesterification of Acrylate Derivatives for Functionalized Monomer Synthesis Using a Hard Zinc Alkoxide Generation Strategy

Daiki Nakatake, Ryo Yazaki, Takashi Ohshima

研究成果: Contribution to journalArticle査読

4 被引用数 (Scopus)

抄録

A new practical method for the synthesis of functionalized acrylate derivatives with the view to prepare functional polymers was explored. Hard zinc alkoxide generation enabled the highly chemoselective transesterification of acrylate derivatives over the undesired conjugate addition, which caused polymerization. The combined use of the catalytic zinc cluster Zn4(OCOCF3)6O and 4-(dimethylamino)pyridine delivered various functionalized acrylate derivatives through the transesterification of commercially available methyl acrylate derivatives with functionalized alcohols under mild conditions.

本文言語英語
ページ(範囲)3696-3699
ページ数4
ジャーナルEuropean Journal of Organic Chemistry
2016
22
DOI
出版ステータス出版済み - 1 1 2016

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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