Chiral acid-catalyzed asymmetric nazarov reaction: Nucleophilic construction of a quaternary asymmetric center at the a-position of the keto function

Kentaro Yaji, Mitsuru Shindo

研究成果: Contribution to journalArticle査読

46 被引用数 (Scopus)

抄録

A chiral Lewis acid catalyzed enantioselective Nazarov reaction affording -alkoxy cyclopentenones has been developed. This is the first example for construction of an asymmetric quaternary center by using the monodentate coordinated divinyl ketones via the interrupted Nazarov reaction, which involves a nucleophilic attack of an alcohol on the -position of the keto function.

本文言語英語
ページ(範囲)2524-2528
ページ数5
ジャーナルSynlett
15
DOI
出版ステータス出版済み - 2009

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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