Chiral Interlocked Corrole Dimers Directly Linked at Inner Carbon Atoms of Confused Pyrrole Rings

Yogesh Kumar Maurya, Pingchun Wei, Takahide Shimada, Kazuhisa Yamasumi, Shigeki Mori, Ko Furukawa, Hajime Kusaba, Tatsumi Ishihara, Yongshu Xie, Masatoshi Ishida, Hiroyuki Furuta

研究成果: Contribution to journalArticle査読

抄録

A facile synthetic strategy towards conformationally stable chiral chromophores based on dimeric porphyrinoids has been established. A peculiar class of face-to-face intramolecularly interlocked corrole dimers were formed by the oxidative C−C coupling linked at the inner carbon sites upon simple treatment of copper(II) ions. Their intrinsic electronic structures were modulated by the peripheral corrole ring annulations, which lead to distinct optical properties and redox profiles. The stereogenic carbon centers implemented in the confused corrole skeleton provided a rationale for designing novel chiral materials.

本文言語英語
ページ(範囲)743-747
ページ数5
ジャーナルChemistry - An Asian Journal
16
7
DOI
出版ステータス出版済み - 4 1 2021

All Science Journal Classification (ASJC) codes

  • 生化学
  • 有機化学

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