Chirality control of a Cu(I) complex of boronic-acid-appended phenanthrolines by sugars. A preliminary step toward the total chain helicity control by a chain-end sugar-binding

Masashi Yamamoto, Masayuki Takeuchi, Seiji Shinkai

研究成果: Contribution to journalArticle査読

20 被引用数 (Scopus)

抄録

Compound 1 which has a 1,10-phenanthroline moiety to constitute the helical structure and a boronic acid moiety to bind saccharides was synthesized. The Cu(I) complex (as 12·Cu(I)) gave the different CD spectra reflecting the helicity, which is regulated by the absolute configurational structure of saccharides. Thus, the P versus M helicity of the complex can be controlled by the boronic acid-saccharide interaction. The results show that the terminal boronic acid group is useful to create chiral helical structure, the helicity of which is governed by a sugar library.

本文言語英語
ページ(範囲)1189-1192
ページ数4
ジャーナルTetrahedron Letters
39
10
DOI
出版ステータス出版済み - 3 5 1998

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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