Chiroselective transcription of the sugar structure to Δ- or Λ-[CoIII(bpy)3]3+ using a boronic acid-sugar template interaction

Toshihisa Mizuno; Masayuki Takeuchi; Itaru Hamachi; Kazuaki Nakashima; Seiji Shinkai

doi:10.1039/a704041e

Chiroselective transcription of the sugar structure to Δ- or Λ-[Co^III(bpy)₃]³⁺ using a boronic acid-sugar template interaction

Toshihisa Mizuno, Masayuki Takeuchi, Itaru Hamachi, Kazuaki Nakashima, Seiji Shinkai

高等研究院

研究成果: Contribution to journal › Article › 査読

30 被引用数 (Scopus)

抄録

In order to apply boronic acid-saccharide interactions to the chiroselective synthesis of Δ- and Λ-[Co^III(bpy)₃]³⁺ a saccharide-binding ligand, 2,2′-bipyridine-4,4′-diboronic acid (bpyba) is newly synthesized; the enantiomeric excess under the optimum reaction conditions reached 79% ee!.

本文言語	英語
ページ（範囲）	1793-1794
ページ数	2
ジャーナル	Chemical Communications
号	18
DOI	https://doi.org/10.1039/a704041e
出版ステータス	出版済み - 1 1 1997

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

文献へのアクセス

10.1039/a704041e

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引用スタイル

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abstract = "In order to apply boronic acid-saccharide interactions to the chiroselective synthesis of Δ- and Λ-[CoIII(bpy)3]3+ a saccharide-binding ligand, 2,2′-bipyridine-4,4′-diboronic acid (bpyba) is newly synthesized; the enantiomeric excess under the optimum reaction conditions reached 79% ee!.",

author = "Toshihisa Mizuno and Masayuki Takeuchi and Itaru Hamachi and Kazuaki Nakashima and Seiji Shinkai",

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AU - Nakashima, Kazuaki

AU - Shinkai, Seiji

PY - 1997/1/1

Y1 - 1997/1/1

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