Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine

Takamasa Miyazaki, Hiromasa Tanaka, Yoshiaki Tanabe, Masahiro Yuki, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

研究成果: Contribution to journalArticle査読

69 被引用数 (Scopus)

抄録

The Ni≡N bond of molecular dinitrogen bridging two molybdenum atoms in the pentamethylcyclopentadienyl molybdenum complexes that bear ferrocenyldiphosphine as an auxiliary ligand is homolytically cleaved under visible light irradiation at room temperature to afford two molar molybdenum nitride complexes. Conversely, the bridging molecular dinitrogen is reformed by the oxidation of the molybdenum nitride complex at room temperature. This result provides a successful example of the cleavage and formation of molecular dinitrogen induced by a pair of two different external stimuli using a single system assisted by molybdenum complexes bearing ferrocenyldiphosphine under ambient conditions.

本文言語英語
ページ(範囲)11488-11492
ページ数5
ジャーナルAngewandte Chemie - International Edition
53
43
DOI
出版ステータス出版済み - 10 20 2014

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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