Cleavage of C-H bond of methane on intermediate Q of methane monooxygenase

Kazunari Yoshizawa, Takehiro Ohta, Yoshihito Shiota, Tokio Yamabe

研究成果: ジャーナルへの寄稿記事

15 引用 (Scopus)

抄録

A possible reaction pathway for the C-H bond cleavage of methane on intermediate Q of methane monooxygenase is studied theoretically. We propose that the activation of methane C-H bond by Q, suggested to involve a high valent Fe2(μ-O)2 diamond core, should occur through the formation of the Q(CH4) complex with an Fe-C bond and Fe-H bonds, followed by a concerted H atom abstraction via a four-centered transition state.

元の言語英語
ページ(範囲)1213-1214
ページ数2
ジャーナルChemistry Letters
発行部数12
DOI
出版物ステータス出版済み - 1 1 1997
外部発表Yes

Fingerprint

methane monooxygenase
Methane
Diamond
Chemical activation
Atoms

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

これを引用

Cleavage of C-H bond of methane on intermediate Q of methane monooxygenase. / Yoshizawa, Kazunari; Ohta, Takehiro; Shiota, Yoshihito; Yamabe, Tokio.

:: Chemistry Letters, 番号 12, 01.01.1997, p. 1213-1214.

研究成果: ジャーナルへの寄稿記事

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