Cobalt "single-coronet" porphyrin bearing hydroxyl groups in its O2 binding site as a new model for myoglobin and hemoglobin: Observation of unusually low frequency of v(O-O) in resonance Raman spectrum

Shinya Nakayama, Fumito Tani, Mikiya Matsu-Ura, Yoshinori Naruta

研究成果: Contribution to journalArticle査読

7 被引用数 (Scopus)

抄録

The resonance Raman spectrum of oxy CoSCP with AdIm(2-H) showed an unusually low v(O-O) frequency at 1123 cm-1. This result is due to the cooperative effect of strong donation from AdIm(2-H) and hydrogen bonding between the inner hydroxyl groups and coordinated dioxygen.

本文言語英語
ページ(範囲)496-497
ページ数2
ジャーナルChemistry Letters
5
DOI
出版ステータス出版済み - 5 5 2002

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

フィンガープリント

「Cobalt "single-coronet" porphyrin bearing hydroxyl groups in its O<sub>2</sub> binding site as a new model for myoglobin and hemoglobin: Observation of unusually low frequency of v(O-O) in resonance Raman spectrum」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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