Coenzyme models. Part 16. Studies of general-acid catalysis in the NADH model reduction

Seiji Shinkai, Hisatake Hamada, Yumiko Kusano, Osamu Manabe

研究成果: ジャーナルへの寄稿 › 記事

40 引用 (Scopus)

抄録

The reduction of trifluoroacetophenone was performed in an aqueous acetate (and analogues) buffer solution with an acid-stable NADH model compound, 1-benzyl-3-carbamoyl-1,4-dihydroquinoline. The resultant Brönsted plots had a slope of -0.20, indicating that the reduction process is general-acid catalysed. This is the first example of general-acid catalysis observed in an NADH model reduction performed in an aqueous system.

元の言語英語
ページ（範囲）699-702
ページ数4
ジャーナルJournal of the Chemical Society, Perkin Transactions 2
発行部数5
DOI
出版物ステータス出版済み - 1 1 1979

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Coenzymes
NAD
Catalysis
Acids
Buffers
Acetates

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

これを引用

Coenzyme models. Part 16. Studies of general-acid catalysis in the NADH model reduction. / Shinkai, Seiji; Hamada, Hisatake; Kusano, Yumiko; Manabe, Osamu.

：: Journal of the Chemical Society, Perkin Transactions 2, 番号 5, 01.01.1979, p. 699-702.

研究成果: ジャーナルへの寄稿 › 記事

Shinkai, S, Hamada, H, Kusano, Y & Manabe, O 1979, 'Coenzyme models. Part 16. Studies of general-acid catalysis in the NADH model reduction', Journal of the Chemical Society, Perkin Transactions 2, 番号 5, pp. 699-702. https://doi.org/10.1039/P29790000699
Shinkai S, Hamada H, Kusano Y, Manabe O. Coenzyme models. Part 16. Studies of general-acid catalysis in the NADH model reduction. Journal of the Chemical Society, Perkin Transactions 2. 1979 1 1;(5):699-702. https://doi.org/10.1039/P29790000699
Shinkai, Seiji ; Hamada, Hisatake ; Kusano, Yumiko ; Manabe, Osamu. / Coenzyme models. Part 16. Studies of general-acid catalysis in the NADH model reduction. ：: Journal of the Chemical Society, Perkin Transactions 2. 1979 ; 番号 5. pp. 699-702.
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