抜粋
The reduction of trifluoroacetophenone was performed in an aqueous acetate (and analogues) buffer solution with an acid-stable NADH model compound, 1-benzyl-3-carbamoyl-1,4-dihydroquinoline. The resultant Brönsted plots had a slope of -0.20, indicating that the reduction process is general-acid catalysed. This is the first example of general-acid catalysis observed in an NADH model reduction performed in an aqueous system.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 699-702 |
| ページ数 | 4 |
| ジャーナル | Journal of the Chemical Society, Perkin Transactions 2 |
| 発行部数 | 5 |
| DOI | |
| 出版物ステータス | 出版済み - 1 1 1979 |
| 外部発表 | Yes |
All Science Journal Classification (ASJC) codes
- Chemistry(all)
フィンガープリント Coenzyme models. Part 16. Studies of general-acid catalysis in the NADH model reduction' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。
これを引用
Shinkai, S., Hamada, H., Kusano, Y., & Manabe, O. (1979). Coenzyme models. Part 16. Studies of general-acid catalysis in the NADH model reduction. Journal of the Chemical Society, Perkin Transactions 2, (5), 699-702. https://doi.org/10.1039/P29790000699