Coenzyme models. Part 35. Charge separation on the micelle surface as a strategy to prove the multi-step reaction mechanism in NADH model reductions

Seiji Shinkai, Takaharu Tsuno, Yukiko Asatani, Osamu Manabe

研究成果: Contribution to journalArticle査読

17 被引用数 (Scopus)

抄録

We have found that (i) the reaction of NADH model compounds with potassium persulphate (PPS) in anionic and non-ionic micelles initiates radical polymerisation of acrylamide and (ii) that reductive desulphonation of 2,4,6-trinitrobenzenesulphonate and 4-carboxy-2,6-dinitrobenzenesulphonate by NADH model compounds in deuterium oxide in the presence of the micelles gives 1,3,5-trinitrobenzene and 3,5-dinitrobenzoic acid, respectively, which contain 3-16% deuterium. The results indicate that the reactions proceed through multi-step hydrogen transfer via radical ion-pair intermediates and the micelle is capable of dissociating the radical ion-pairs.

本文言語英語
ページ(範囲)1533-1540
ページ数8
ジャーナルJournal of the Chemical Society, Perkin Transactions 2
9
DOI
出版ステータス出版済み - 1 1 1983
外部発表はい

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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