TY - JOUR
T1 - Cohelical crossover network by supramolecular polymerization of a 4, 6-acetalized β-1, 3-glucan macromer
AU - Sakamoto, Junji
AU - Kita, Rio
AU - Duelamae, Isala
AU - Kunitake, Masashi
AU - Hirano, Megumi
AU - Yoshihara, Daisuke
AU - Yamamoto, Tatsuhiro
AU - Noguchi, Takao
AU - Roy, Bappaditya
AU - Shinkai, Seiji
N1 - Funding Information:
The authors thank Prof. Y. Miura and Mr. M. Nagao (Kyushu Univ., Japan) for access to the GPC apparatus in their laboratory and kind instruction. This work was supported partly by JSPS Grant-in-Aid for Scientific Research(B) JP26288102 and MEXT-Supported Program for the Strategic Research Foundation at Private Universities.
Publisher Copyright:
© 2016 American Chemical Society.
PY - 2017/1/17
Y1 - 2017/1/17
N2 - Natural polysaccharides represent a renewable resource whose effective utilization is of increasing importance. Chemical modification is a powerful tool to transform them into processable materials but usually sacrifices the original structures and properties of value. Here we introduce a chemical modification of Curdlan, a β-1, 3-glucan, via 4, 6-acetalization. This modification has successfully combined a helix-forming ability of Curdlan with new solubility in organic media. Furthermore, it has operationalized efficient cohelical crossovers (CCs) among the helices to demonstrate the formation of an extensive supramolecular network that goes well beyond the nanoscopic regime, allowing for preparation of flexible self-supporting films with macroscopic dimensions. This protocol, which is now viewed as supramolecular polymerization of a helical polysaccharide macromer, can add a new dimension to "polysaccharide nanotechnology", opening a door for the creation of unconventional polymer materials based on the cohelical crossover network (CCN).
AB - Natural polysaccharides represent a renewable resource whose effective utilization is of increasing importance. Chemical modification is a powerful tool to transform them into processable materials but usually sacrifices the original structures and properties of value. Here we introduce a chemical modification of Curdlan, a β-1, 3-glucan, via 4, 6-acetalization. This modification has successfully combined a helix-forming ability of Curdlan with new solubility in organic media. Furthermore, it has operationalized efficient cohelical crossovers (CCs) among the helices to demonstrate the formation of an extensive supramolecular network that goes well beyond the nanoscopic regime, allowing for preparation of flexible self-supporting films with macroscopic dimensions. This protocol, which is now viewed as supramolecular polymerization of a helical polysaccharide macromer, can add a new dimension to "polysaccharide nanotechnology", opening a door for the creation of unconventional polymer materials based on the cohelical crossover network (CCN).
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U2 - 10.1021/acsmacrolett.6b00706
DO - 10.1021/acsmacrolett.6b00706
M3 - Article
C2 - 35632874
AN - SCOPUS:85037091405
VL - 6
SP - 21
EP - 26
JO - ACS Macro Letters
JF - ACS Macro Letters
SN - 2161-1653
IS - 1
ER -
