Comparative SANS and SAXS studies on a mesoscopically heterogeneous structure in the dehydrated NIPA/SA gel

Masaaki Sugiyama, Annaka Masahiko, Ryuhei Motokawa, Shuichiro Kuwajima, Kazuhiro Hara

研究成果: ジャーナルへの寄稿記事

7 引用 (Scopus)


Mesoscopic structures of a dehydrated N-isopropylacrylamide/sodium acrylate (NIPA/SA) gel and the re-moistened one are investigated with complementary use of the small-angle X-ray scattering (SAXS) and small-angle neutron scattering (SANS) methods. The SAXS profile of the dehydrated NIPA/SA gel shows a clear peak at q = 0.026 Å-1 but that of the re-moistened one does not. On the other hand, only the SANS profile of the re-moistened NIPA/SA gel shows a peak at q = 0.022 Å-1. Taking into account that SAXS is sensitive to the fluctuation of the distribution of the SA bases and SANS is sensitive to that of the water in the NIPA/SA gel, these results indicate that inhomogeneous evaporation of water in the NIPA/SA gel occurs on the dehydration and that the SA clusters are finally generated.

ジャーナルPhysica B: Condensed Matter
出版物ステータス出版済み - 1 1 2002


All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics