Comparison of interdiffusion behavior between linear polystyrenes and cyclic polystyrenes with same molecular weight

Daisuke Kawaguchi, Atsushi Takano, Yushu Matsushita, Naoya Torikai, Keiji Tanaka, Toshihiko Nagamura, Robert Dalgliesh, Sean Langridge

研究成果: Contribution to conferencePaper

抜粋

Time evolution of interfacial thicknesses between a cyclic polystyrene (c-hPS) / its deuterated counterpart (c-dPS) and a linear polystyrene (1-hPS) / its deuterated counterpart (1-dPS) bilayer films was investigated by dynamic secondary ion mass spectrometry (DSIMS) and neutron reflectivity (NR). The interfacial thickness of (c-hPS/c-dPS) film was significantly larger than that of (1-hPS/1-dPS) film at any given annealing time, indicating that the diffusion constant of c-PS is constantly larger than that of 1-PS. It might be explained that weaker topological constraint comes from the entanglement for the c-PS than for the 1-PS.

元の言語英語
ページ数1
出版物ステータス出版済み - 12 1 2005
イベント54th SPSJ Symposium on Macromolecules - Yamagata, 日本
継続期間: 9 20 20059 22 2005

その他

その他54th SPSJ Symposium on Macromolecules
日本
Yamagata
期間9/20/059/22/05

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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  • これを引用

    Kawaguchi, D., Takano, A., Matsushita, Y., Torikai, N., Tanaka, K., Nagamura, T., Dalgliesh, R., & Langridge, S. (2005). Comparison of interdiffusion behavior between linear polystyrenes and cyclic polystyrenes with same molecular weight. 論文発表場所 54th SPSJ Symposium on Macromolecules, Yamagata, 日本.