Complex chemistry with complex compounds

Robert Eichler, M. Asai, H. Brand, N. M. Chiera, A. Di Nitto, R. Dressler, Ch E. Düllmann, J. Even, F. Fangli, M. Goetz, H. Haba, W. Hartmann, E. Jäger, D. Kaji, J. Kanaya, Y. Kaneya, J. Khuyagbaatar, B. Kindler, Y. Komori, B. KrausJ. V. Kratz, J. Krier, Y. Kudou, N. Kurz, S. Miyashita, K. Morimoto, K. Morita, M. Murakami, Y. Nagame, K. Ooe, D. Piguet, N. Sato, T. K. Sato, J. Steiner, P. Steinegger, T. Sumita, M. Takeyama, K. Tanaka, T. Tomitsuka, A. Toyoshima, K. Tsukada, A. Türler, I. Usoltsev, Y. Wakabayashi, Y. Wang, N. Wiehl, Y. Wittwer, A. Yakushev, S. Yamaki, S. Yano, S. Yamaki, Z. Qin

研究成果: 著書/レポートタイプへの貢献会議での発言

1 引用 (Scopus)

抄録

In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the investigation of fragile single molecular species by gas-phase chromatography. The latest success with the heaviest group 6 transactinide seaborgium is highlighted. The formation of a very volatile hexacarbonyl compound Sg(CO)6 was observed similarly to its lighter homologues molybdenum and tungsten. The interactions of these gaseous carbonyl complex compounds with quartz surfaces were investigated by thermochromatography. Second-generation experiments are under way to investigate the intramolecular bond between the central metal atom of the complexes and the ligands addressing the influence of relativistic effects in the heaviest compounds. Our contribution comprises some aspects of the ongoing challenging experiments as well as an outlook towards other interesting compounds related to volatile complex compounds in the gas phase.

元の言語英語
ホスト出版物のタイトルNobel Symposium NS 160 - Chemistry and Physics of Heavy and Superheavy Elements
編集者Dirk Rudolph
出版者EDP Sciences
ISBN(電子版)9782759890118
DOI
出版物ステータス出版済み - 12 1 2016
イベント2016 Nobel Symposium NS 160 - Chemistry and Physics of Heavy and Superheavy Elements - Fjalkinge, スウェーデン
継続期間: 5 29 20166 3 2016

出版物シリーズ

名前EPJ Web of Conferences
131
ISSN(印刷物)2101-6275
ISSN(電子版)2100-014X

その他

その他2016 Nobel Symposium NS 160 - Chemistry and Physics of Heavy and Superheavy Elements
スウェーデン
Fjalkinge
期間5/29/166/3/16

Fingerprint

complex compounds
chemistry
vapor phases
seaborgium
chromatography
relativistic effects
molybdenum
tungsten
quartz
ligands
metals
atoms
interactions

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

これを引用

Eichler, R., Asai, M., Brand, H., Chiera, N. M., Di Nitto, A., Dressler, R., ... Qin, Z. (2016). Complex chemistry with complex compounds. : D. Rudolph (版), Nobel Symposium NS 160 - Chemistry and Physics of Heavy and Superheavy Elements [07005] (EPJ Web of Conferences; 巻数 131). EDP Sciences. https://doi.org/10.1051/epjconf/201613107005

Complex chemistry with complex compounds. / Eichler, Robert; Asai, M.; Brand, H.; Chiera, N. M.; Di Nitto, A.; Dressler, R.; Düllmann, Ch E.; Even, J.; Fangli, F.; Goetz, M.; Haba, H.; Hartmann, W.; Jäger, E.; Kaji, D.; Kanaya, J.; Kaneya, Y.; Khuyagbaatar, J.; Kindler, B.; Komori, Y.; Kraus, B.; Kratz, J. V.; Krier, J.; Kudou, Y.; Kurz, N.; Miyashita, S.; Morimoto, K.; Morita, K.; Murakami, M.; Nagame, Y.; Ooe, K.; Piguet, D.; Sato, N.; Sato, T. K.; Steiner, J.; Steinegger, P.; Sumita, T.; Takeyama, M.; Tanaka, K.; Tomitsuka, T.; Toyoshima, A.; Tsukada, K.; Türler, A.; Usoltsev, I.; Wakabayashi, Y.; Wang, Y.; Wiehl, N.; Wittwer, Y.; Yakushev, A.; Yamaki, S.; Yano, S.; Yamaki, S.; Qin, Z.

Nobel Symposium NS 160 - Chemistry and Physics of Heavy and Superheavy Elements. 版 / Dirk Rudolph. EDP Sciences, 2016. 07005 (EPJ Web of Conferences; 巻 131).

研究成果: 著書/レポートタイプへの貢献会議での発言

Eichler, R, Asai, M, Brand, H, Chiera, NM, Di Nitto, A, Dressler, R, Düllmann, CE, Even, J, Fangli, F, Goetz, M, Haba, H, Hartmann, W, Jäger, E, Kaji, D, Kanaya, J, Kaneya, Y, Khuyagbaatar, J, Kindler, B, Komori, Y, Kraus, B, Kratz, JV, Krier, J, Kudou, Y, Kurz, N, Miyashita, S, Morimoto, K, Morita, K, Murakami, M, Nagame, Y, Ooe, K, Piguet, D, Sato, N, Sato, TK, Steiner, J, Steinegger, P, Sumita, T, Takeyama, M, Tanaka, K, Tomitsuka, T, Toyoshima, A, Tsukada, K, Türler, A, Usoltsev, I, Wakabayashi, Y, Wang, Y, Wiehl, N, Wittwer, Y, Yakushev, A, Yamaki, S, Yano, S, Yamaki, S & Qin, Z 2016, Complex chemistry with complex compounds. : D Rudolph (版), Nobel Symposium NS 160 - Chemistry and Physics of Heavy and Superheavy Elements., 07005, EPJ Web of Conferences, 巻. 131, EDP Sciences, 2016 Nobel Symposium NS 160 - Chemistry and Physics of Heavy and Superheavy Elements, Fjalkinge, スウェーデン, 5/29/16. https://doi.org/10.1051/epjconf/201613107005
Eichler R, Asai M, Brand H, Chiera NM, Di Nitto A, Dressler R その他. Complex chemistry with complex compounds. : Rudolph D, 編集者, Nobel Symposium NS 160 - Chemistry and Physics of Heavy and Superheavy Elements. EDP Sciences. 2016. 07005. (EPJ Web of Conferences). https://doi.org/10.1051/epjconf/201613107005
Eichler, Robert ; Asai, M. ; Brand, H. ; Chiera, N. M. ; Di Nitto, A. ; Dressler, R. ; Düllmann, Ch E. ; Even, J. ; Fangli, F. ; Goetz, M. ; Haba, H. ; Hartmann, W. ; Jäger, E. ; Kaji, D. ; Kanaya, J. ; Kaneya, Y. ; Khuyagbaatar, J. ; Kindler, B. ; Komori, Y. ; Kraus, B. ; Kratz, J. V. ; Krier, J. ; Kudou, Y. ; Kurz, N. ; Miyashita, S. ; Morimoto, K. ; Morita, K. ; Murakami, M. ; Nagame, Y. ; Ooe, K. ; Piguet, D. ; Sato, N. ; Sato, T. K. ; Steiner, J. ; Steinegger, P. ; Sumita, T. ; Takeyama, M. ; Tanaka, K. ; Tomitsuka, T. ; Toyoshima, A. ; Tsukada, K. ; Türler, A. ; Usoltsev, I. ; Wakabayashi, Y. ; Wang, Y. ; Wiehl, N. ; Wittwer, Y. ; Yakushev, A. ; Yamaki, S. ; Yano, S. ; Yamaki, S. ; Qin, Z. / Complex chemistry with complex compounds. Nobel Symposium NS 160 - Chemistry and Physics of Heavy and Superheavy Elements. 編集者 / Dirk Rudolph. EDP Sciences, 2016. (EPJ Web of Conferences).
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abstract = "In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the investigation of fragile single molecular species by gas-phase chromatography. The latest success with the heaviest group 6 transactinide seaborgium is highlighted. The formation of a very volatile hexacarbonyl compound Sg(CO)6 was observed similarly to its lighter homologues molybdenum and tungsten. The interactions of these gaseous carbonyl complex compounds with quartz surfaces were investigated by thermochromatography. Second-generation experiments are under way to investigate the intramolecular bond between the central metal atom of the complexes and the ligands addressing the influence of relativistic effects in the heaviest compounds. Our contribution comprises some aspects of the ongoing challenging experiments as well as an outlook towards other interesting compounds related to volatile complex compounds in the gas phase.",
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T1 - Complex chemistry with complex compounds

AU - Eichler, Robert

AU - Asai, M.

AU - Brand, H.

AU - Chiera, N. M.

AU - Di Nitto, A.

AU - Dressler, R.

AU - Düllmann, Ch E.

AU - Even, J.

AU - Fangli, F.

AU - Goetz, M.

AU - Haba, H.

AU - Hartmann, W.

AU - Jäger, E.

AU - Kaji, D.

AU - Kanaya, J.

AU - Kaneya, Y.

AU - Khuyagbaatar, J.

AU - Kindler, B.

AU - Komori, Y.

AU - Kraus, B.

AU - Kratz, J. V.

AU - Krier, J.

AU - Kudou, Y.

AU - Kurz, N.

AU - Miyashita, S.

AU - Morimoto, K.

AU - Morita, K.

AU - Murakami, M.

AU - Nagame, Y.

AU - Ooe, K.

AU - Piguet, D.

AU - Sato, N.

AU - Sato, T. K.

AU - Steiner, J.

AU - Steinegger, P.

AU - Sumita, T.

AU - Takeyama, M.

AU - Tanaka, K.

AU - Tomitsuka, T.

AU - Toyoshima, A.

AU - Tsukada, K.

AU - Türler, A.

AU - Usoltsev, I.

AU - Wakabayashi, Y.

AU - Wang, Y.

AU - Wiehl, N.

AU - Wittwer, Y.

AU - Yakushev, A.

AU - Yamaki, S.

AU - Yano, S.

AU - Yamaki, S.

AU - Qin, Z.

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