Conformational Relaxation of Poly(styrene- co -butadiene) Chains at Substrate Interface in Spin-Coated and Solvent-Cast Films

Biao Zuo, Manabu Inutsuka, Daisuke Kawaguchi, Xinping Wang, Keiji Tanaka

研究成果: ジャーナルへの寄稿記事

12 引用 (Scopus)

抄録

The local conformation of poly(styrene-co-butadiene) rubber (SBR) chains in direct contact with a quartz substrate was examined by interface-sensitive sum-frequency generation (SFG) spectroscopy. SFG signals, which could be obtained from functional groups only oriented at the interface, were clearly observed for SBR in a film at room temperature which was much higher than the bulk glass transition temperature (Tg). When the film was thermally annealed, SBR chains at the quartz interface changed their conformation to one with a lower energy state, accompanied by the randomization of both the main and side chain parts. The characteristic temperature, at which interfacial chains started to lose their orientations, was much higher than the bulk Tg. Also, the extent found to be more remarkable for the spin-coated film than for the solvent-cast one. This implies that the stress accumulated at the interface, which resulted from the centrifugal force during the spin-coating process, accelerates the mobility of chains there. Finally, the kinetics experiment well supports the slower orientation relaxation at the interface.

元の言語英語
ページ(範囲)2180-2186
ページ数7
ジャーナルMacromolecules
51
発行部数6
DOI
出版物ステータス出版済み - 3 27 2018

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Styrene
Rubber
Butadiene
Quartz
Conformations
Substrates
Spin coating
Electron energy levels
Functional groups
Spectroscopy
Temperature
Kinetics
1,3-butadiene
Experiments

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

これを引用

Conformational Relaxation of Poly(styrene- co -butadiene) Chains at Substrate Interface in Spin-Coated and Solvent-Cast Films. / Zuo, Biao; Inutsuka, Manabu; Kawaguchi, Daisuke; Wang, Xinping; Tanaka, Keiji.

:: Macromolecules, 巻 51, 番号 6, 27.03.2018, p. 2180-2186.

研究成果: ジャーナルへの寄稿記事

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abstract = "The local conformation of poly(styrene-co-butadiene) rubber (SBR) chains in direct contact with a quartz substrate was examined by interface-sensitive sum-frequency generation (SFG) spectroscopy. SFG signals, which could be obtained from functional groups only oriented at the interface, were clearly observed for SBR in a film at room temperature which was much higher than the bulk glass transition temperature (Tg). When the film was thermally annealed, SBR chains at the quartz interface changed their conformation to one with a lower energy state, accompanied by the randomization of both the main and side chain parts. The characteristic temperature, at which interfacial chains started to lose their orientations, was much higher than the bulk Tg. Also, the extent found to be more remarkable for the spin-coated film than for the solvent-cast one. This implies that the stress accumulated at the interface, which resulted from the centrifugal force during the spin-coating process, accelerates the mobility of chains there. Finally, the kinetics experiment well supports the slower orientation relaxation at the interface.",
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AU - Kawaguchi, Daisuke

AU - Wang, Xinping

AU - Tanaka, Keiji

PY - 2018/3/27

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N2 - The local conformation of poly(styrene-co-butadiene) rubber (SBR) chains in direct contact with a quartz substrate was examined by interface-sensitive sum-frequency generation (SFG) spectroscopy. SFG signals, which could be obtained from functional groups only oriented at the interface, were clearly observed for SBR in a film at room temperature which was much higher than the bulk glass transition temperature (Tg). When the film was thermally annealed, SBR chains at the quartz interface changed their conformation to one with a lower energy state, accompanied by the randomization of both the main and side chain parts. The characteristic temperature, at which interfacial chains started to lose their orientations, was much higher than the bulk Tg. Also, the extent found to be more remarkable for the spin-coated film than for the solvent-cast one. This implies that the stress accumulated at the interface, which resulted from the centrifugal force during the spin-coating process, accelerates the mobility of chains there. Finally, the kinetics experiment well supports the slower orientation relaxation at the interface.

AB - The local conformation of poly(styrene-co-butadiene) rubber (SBR) chains in direct contact with a quartz substrate was examined by interface-sensitive sum-frequency generation (SFG) spectroscopy. SFG signals, which could be obtained from functional groups only oriented at the interface, were clearly observed for SBR in a film at room temperature which was much higher than the bulk glass transition temperature (Tg). When the film was thermally annealed, SBR chains at the quartz interface changed their conformation to one with a lower energy state, accompanied by the randomization of both the main and side chain parts. The characteristic temperature, at which interfacial chains started to lose their orientations, was much higher than the bulk Tg. Also, the extent found to be more remarkable for the spin-coated film than for the solvent-cast one. This implies that the stress accumulated at the interface, which resulted from the centrifugal force during the spin-coating process, accelerates the mobility of chains there. Finally, the kinetics experiment well supports the slower orientation relaxation at the interface.

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