Construction of a fully substituted cyclopentenone as the core skeleton of stemonamide via a Nazarov cyclization

Kentaro Yaji, Mitsuru Shindo

研究成果: Contribution to journalArticle査読

13 被引用数 (Scopus)

抄録

A synthetic study of the Stemona alkaloid stemonamide is described. The FeCl3-promoted fast Nazarov reaction of β-alkoxy divinyl ketones in the presence of t-BuOH afforded an α-methylene cyclopentenone, which was subsequently subjected to the Rh-catalyzed C-H amination to provide a fully appropriately substituted α-methylene cyclopentenone as the core skeleton of stemonamide.

本文言語英語
ページ(範囲)5469-5472
ページ数4
ジャーナルTetrahedron Letters
51
41
DOI
出版ステータス出版済み - 10 13 2010

All Science Journal Classification (ASJC) codes

  • 生化学
  • 創薬
  • 有機化学

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