Control of single supramolecular chain of porphyrin on a copper surface

T. Kamikado, T. Sekiguchi, Shiyoshi Yokoyama, Y. Wakayama, S. Mashiko

研究成果: ジャーナルへの寄稿Conference article

14 引用 (Scopus)


The initial growth behavior and structures of free base and metal complexes of 5,10,15,20-tetrakis(3,5-di-t-butylphenyl)porphyrin (H2-TBPP, M-TBPP) on Cu(100) surface were studied by scanning tunneling microscopy. Conformational flexibility of H2-TBPP led to bridging over the step edges and to formation of single supramolecular chains on the step edges, which were separated from the supramolecular islands on the terraces. M-TBPP adsorbed on the upper and lower edge of the step and 2D growth of islands began from here. These results suggest that the step edges could be useful as a template for fabrication of well-ordered single supramolecular chains.

ジャーナルThin Solid Films
出版物ステータス出版済み - 3 21 2006
イベントProceedings of the Sixth International Conference on Nano-Molecular Electronics (ICNME 2004) -
継続期間: 12 15 200412 17 2004

All Science Journal Classification (ASJC) codes

  • Surfaces, Coatings and Films
  • Condensed Matter Physics
  • Surfaces and Interfaces

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