Control of the dual emission from a thermally activated delayed fluorescence emitter containing phenothiazine units in organic light-emitting diodes

Ikbal Marghad, Fatima Bencheikh, Chao Wang, Sophia Manolikakes, Alice Rérat, Corinne Gosmini, Dae Hyeon Kim, Jean Charles Ribierre, Chihaya Adachi

研究成果: ジャーナルへの寄稿記事

2 引用 (Scopus)

抄録

The development of single-component organic dual light-emitting molecules is of interest for a range of applications including white organic light-emitting diodes. Herein, a new thermally-activated delayed fluorescent molecule containing 4,6-bis-phenyl phenothiazine as donor units and 2-thiophene-1,3,5-triazine as acceptor unit was synthesized using a simple cost-effective method. This compound shows two stable molecular conformations due to the presence of the phenothiazine units in its molecular structure. These conformers exhibit different photophysical properties in both solution and thin films. The electroluminescence properties of this novel emitter were then examined in organic light-emitting diodes and the results provide useful insights into the influence of the device architecture on the dual emission characteristics. The experimental results were consistent with the optical simulations and the optimized architecture led to the fabrication of electroluminescent devices with an external quantum efficiency of 11.5% and a maximum luminance value of 10370 cd m -2 .

元の言語英語
ページ(範囲)4336-4343
ページ数8
ジャーナルRSC Advances
9
発行部数8
DOI
出版物ステータス出版済み - 1 1 2019

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Organic light emitting diodes (OLED)
Fluorescence
Luminescent devices
Thiophenes
Triazines
Molecules
Electroluminescence
Thiophene
Quantum efficiency
Molecular structure
Conformations
Luminance
Fabrication
Thin films
Costs
phenothiazine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

これを引用

Control of the dual emission from a thermally activated delayed fluorescence emitter containing phenothiazine units in organic light-emitting diodes. / Marghad, Ikbal; Bencheikh, Fatima; Wang, Chao; Manolikakes, Sophia; Rérat, Alice; Gosmini, Corinne; Kim, Dae Hyeon; Ribierre, Jean Charles; Adachi, Chihaya.

:: RSC Advances, 巻 9, 番号 8, 01.01.2019, p. 4336-4343.

研究成果: ジャーナルへの寄稿記事

Marghad, I, Bencheikh, F, Wang, C, Manolikakes, S, Rérat, A, Gosmini, C, Kim, DH, Ribierre, JC & Adachi, C 2019, 'Control of the dual emission from a thermally activated delayed fluorescence emitter containing phenothiazine units in organic light-emitting diodes', RSC Advances, 巻. 9, 番号 8, pp. 4336-4343. https://doi.org/10.1039/c8ra10393c
Marghad, Ikbal ; Bencheikh, Fatima ; Wang, Chao ; Manolikakes, Sophia ; Rérat, Alice ; Gosmini, Corinne ; Kim, Dae Hyeon ; Ribierre, Jean Charles ; Adachi, Chihaya. / Control of the dual emission from a thermally activated delayed fluorescence emitter containing phenothiazine units in organic light-emitting diodes. :: RSC Advances. 2019 ; 巻 9, 番号 8. pp. 4336-4343.
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AU - Rérat, Alice

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