Coordination structure changes of linear cobalt(II) triazole complexes induced by binding of long-chained alcohols: Adaptive molecular clefts

Keita Kuroiwa, Nobuo Kimizuka

研究成果: Contribution to journalArticle査読

13 被引用数 (Scopus)

抄録

Lipophilic, linear cobalt(II) triazole complex Co(1)3Cl 2 in chloroform shows sol-to-gel transition upon addition of long-chained alcohols. Binding of alcohol molecules induces coordination structure changes (octahedral, Oh to tetrahedral, Td), which promotes aggregation of nanofibers and concomitant physical gelation. The surface of lipophilic, linear complexes provides binding sites for guest molecules, which is referred to as adaptive molecular clefts.

本文言語英語
ページ(範囲)192-193
ページ数2
ジャーナルChemistry Letters
37
2
DOI
出版ステータス出版済み - 2 5 2008

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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