Copper-mediated direct C(sp3)-H and C(sp2)-H acetoxylation

Zhen Wang, Yoichiro Kuninobu, Motomu Kanai

研究成果: ジャーナルへの寄稿記事

77 引用 (Scopus)

抄録

A copper-mediated terminal position-selective C-(sp3)-H acetoxylation using a bidentate directing group and AgOAc as an oxidant was achieved. This reaction has high functional group tolerance and is not affected by steric hindrance. The reaction proceeds in excellent yield, even in gram scale, and the directing group can be removed after the reaction. Aromatic C(sp2)-H acetoxylation also proceeded under similar reaction conditions.

元の言語英語
ページ(範囲)4790-4793
ページ数4
ジャーナルOrganic Letters
16
発行部数18
DOI
出版物ステータス出版済み - 9 19 2014

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Oxidants
Functional groups
Copper
copper

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

これを引用

Copper-mediated direct C(sp3)-H and C(sp2)-H acetoxylation. / Wang, Zhen; Kuninobu, Yoichiro; Kanai, Motomu.

:: Organic Letters, 巻 16, 番号 18, 19.09.2014, p. 4790-4793.

研究成果: ジャーナルへの寄稿記事

Wang, Zhen ; Kuninobu, Yoichiro ; Kanai, Motomu. / Copper-mediated direct C(sp3)-H and C(sp2)-H acetoxylation. :: Organic Letters. 2014 ; 巻 16, 番号 18. pp. 4790-4793.
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