Covalently Attached Porphycene-Ferrocene Dyads: Synthesis, Redox-Switched Emission, and Observation of the Charge-Separated State

Masaaki Abe, Hiroaki Yamada, Toru Okawara, Mamoru Fujitsuka, Tetsuro Majima, Yoshio Hisaeda

研究成果: Contribution to journalArticle査読

7 被引用数 (Scopus)

抄録

Two new porphycenes functionalized with ferrocenyl pendants have been synthesized and characterized spectroscopically and structurally. The porphycene-based emission in porphycene-ferrocene dyads was switched on and off by the reversible control of the ferrocenyl pendant redox states. Transient absorption spectroscopy with a femtosecond laser-pulsed technique has successfully detected the picosecond charge-separated excited state of the dyad upon Q-band excitation of the porphycene ring.

本文言語英語
ページ(範囲)7-9
ページ数3
ジャーナルInorganic chemistry
55
1
DOI
出版ステータス出版済み - 1 4 2016

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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