Cracking of Polyethylene, Polypropylene, and Polystyrene with Supercritical Water

Atsushi Kishita, Yuichi Sugai, Shinya Takemori, Shingo Koizumi, Fangming Jin, Heiji Enomoto, Takehiko Moriya

研究成果: Contribution to journalArticle査読

3 被引用数 (Scopus)

抄録

In order to obtain the basic data in cracking of PE, PP and PS (addition polymerization plastics), experimental investigation was carried out using supercritical water of density of 0.3 g/cm3 at a temperature of 430°C and a pressure of ca. 42 MPa. It was found that these plastics were easily decomposed to oily materials without coke formation and the time required for liquefaction was in the order of PE>PP>PS. The oily products obtained had the main chemical structure of polymers; normal paraffin’s for PE, and 1,3,5-cyclohexane for PP. For PS, styrene monomer was first produced, with a gradual increase in ethyl benzene toluene and stable poly-phenyl hydrocarbons with 2–4 rings, which were different, from oligomer of styrene. The amount of them increased with reaction time. When a decomposition reaction occurred in alkali solution, the decomposition rate decreased, but the reaction mechanism seemed to be unchanged.

本文言語英語
ページ(範囲)5-13
ページ数9
ジャーナルResources Processing
52
1
DOI
出版ステータス出版済み - 2005
外部発表はい

All Science Journal Classification (ASJC) codes

  • 環境化学
  • 土壌科学
  • 汚染
  • 自然保全および景観保全

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