Creation of novel chiral cryptophanes by a self-assembling method utilizing a pyridyl-Pd(II) interaction

Zhenlin Zhong, Atsushi Ikeda, Seiji Shinkai, Shigeru Sakamoto, Kentaro Yamaguchi

研究成果: Contribution to journalArticle査読

77 被引用数 (Scopus)

抄録

This Letter demonstrates the molecular design of novel self-assembled chiral cryptophanes. Mediated by square-planar Pd(II) complexes, racemic pyridyl cyclotriveratrylene derivative rac-2 self-assembles into mixtures of racemic chiral cryptophanes and meso cryptophanes (1), which interconvert with each other, and the rates are remarkably enhanced by the addition of a slight excess of rac-2. On the other hand, optically resolved P-2 or M-2 self-assembles into the chiral cryptophane as the only product.

本文言語英語
ページ(範囲)1085-1087
ページ数3
ジャーナルOrganic Letters
3
7
DOI
出版ステータス出版済み - 4 5 2001

All Science Journal Classification (ASJC) codes

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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